Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey
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2023
Authors
Jevtović, MimaPevec, Andrej
Turel, Iztok
Radanović, Dušanka
Milčić, Miloš
Gruden, Maja
Zlatar, Matija
Mitić, Dragana
Anđelković, Katarina
Čobeljić, Božidar
Article (Accepted Version)
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In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions.
Keywords:
Schiff base ligands / nickel(II) / nickel(III) / complexes / synthesis / X-ray structure / DFT / syngle crystal / EPRSource:
Inorganic Chemistry Communications, 2023, 158, 111582-Publisher:
- Elsevier
Funding / projects:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-MESTD-inst-2020-200026)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200168 (University of Belgrade, Faculty of Chemistry) (RS-MESTD-inst-2020-200168)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200288 (Innovation Center of the Faculty of Chemistry) (RS-MESTD-inst-2020-200288)
- Slovenian Research Agency (ARRS), grant number P1-0175
Note:
- This is the accepted version of the manuscript: M. Jevtović, A. Pevec, I. Turel, D. Radanović, M. Milčić, M. Gruden, M. Zlatar, D. Mitić, K. Anđelković, B. Čobeljić, Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey, Inorganic Chemistry Communications (2023), doi: https://doi.org/10.1016/j.inoche.2023.111582
- Published version: https://cer.ihtm.bg.ac.rs/handle/123456789/6788
Related info:
- Version of
https://doi.org/10.1016/j.inoche.2023.111582 - Version of
https://cer.ihtm.bg.ac.rs/handle/123456789/6788
Institution/Community
IHTMTY - JOUR AU - Jevtović, Mima AU - Pevec, Andrej AU - Turel, Iztok AU - Radanović, Dušanka AU - Milčić, Miloš AU - Gruden, Maja AU - Zlatar, Matija AU - Mitić, Dragana AU - Anđelković, Katarina AU - Čobeljić, Božidar PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6766 AB - In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions. PB - Elsevier T2 - Inorganic Chemistry Communications T1 - Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey VL - 158 SP - 111582 DO - 10.1016/j.inoche.2023.111582 ER -
@article{ author = "Jevtović, Mima and Pevec, Andrej and Turel, Iztok and Radanović, Dušanka and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Mitić, Dragana and Anđelković, Katarina and Čobeljić, Božidar", year = "2023", abstract = "In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions.", publisher = "Elsevier", journal = "Inorganic Chemistry Communications", title = "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey", volume = "158", pages = "111582", doi = "10.1016/j.inoche.2023.111582" }
Jevtović, M., Pevec, A., Turel, I., Radanović, D., Milčić, M., Gruden, M., Zlatar, M., Mitić, D., Anđelković, K.,& Čobeljić, B.. (2023). Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications Elsevier., 158, 111582. https://doi.org/10.1016/j.inoche.2023.111582
Jevtović M, Pevec A, Turel I, Radanović D, Milčić M, Gruden M, Zlatar M, Mitić D, Anđelković K, Čobeljić B. Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey. in Inorganic Chemistry Communications. 2023;158:111582. doi:10.1016/j.inoche.2023.111582 .
Jevtović, Mima, Pevec, Andrej, Turel, Iztok, Radanović, Dušanka, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Mitić, Dragana, Anđelković, Katarina, Čobeljić, Božidar, "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey" in Inorganic Chemistry Communications, 158 (2023):111582, https://doi.org/10.1016/j.inoche.2023.111582 . .