Performance and mechanisms for Cd(II) and As(III) simultaneous adsorption by goethite-loaded montmorillonite in aqueous solution and soil
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2023
Authors
Zhao, ChenchenYao, Jun
Šolević Knudsen, Tatjana
Liu, Jianli
Zhu, Xiaozhe
Ma, Bo
Li, Hao
Cao, Ying
Liu, Bang
Article (Published version)
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Show full item recordAbstract
A series of goethite-modified montmorillonite (GMt) materials was synthesized for the amelioration of cationic
cadmium (Cd) and anionic arsenic (As) complex contaminants in soil and water bodies. The results showed that
goethite (Gt) was successfully loaded onto the surface of montmorillonite (Mt), which possessed more functional
groups (such as Fe–O, and Fe–OH) and a larger specific surface area. GMt-0.5 (Mt loaded with Gt at a ratio of
0.5:1) showed the highest adsorption capacity for Cd(II) and As(III) with the maximum of 50.61 mg/g and 57.58
mg/g, respectively. The removal rate of Cd(II) was highly pH dependent, while the removal rate of As(III)
showed little dependence on pH. The goethite on montmorillonite might contribute to the formation of surface
complexes with As(III) and oxidation of As(III) to As(V). In the binary system, both, synergistic and competitive
adsorption existed simultaneously. Importantly, in the binary system, the removal of As(III) was more favorable...
because of the electrostatic interaction, formation of a ternary complex, and co-precipitation. In addition, the
amendment of GMt-0.5 significantly reduced the availability of Cd and As in the soil. This study suggests that
GMt-0.5 is a promising candidate for the simultaneous immobilization of metal (loid)s in both, aqueous solution
and mine soil.
Keywords:
Goethite-modified montmorillonite / Cadmium / Arsenic / Simultaneous immobilization / Mine soilSource:
Journal of Environmental Management, 2023, 330, 117163-Publisher:
- Elsevier B.V.
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-MESTD-inst-2020-200026)
- The Chinese Ministry of Science and Technology ( project no 2019YFC1803500)
- The National Science Foundation of China (project no 41720104007)
- The 111 Project (B21017)
- The People’s Republic of China and the Republic of Serbia ( project Number 4–18 )
DOI: 10.1016/j.jenvman.2022.117163
ISSN: 1095-8630; 0301-4797
PubMed: 36603255
WoS: 000920728700001
Scopus: 2-s2.0-85145678191
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Institution/Community
IHTMTY - JOUR AU - Zhao, Chenchen AU - Yao, Jun AU - Šolević Knudsen, Tatjana AU - Liu, Jianli AU - Zhu, Xiaozhe AU - Ma, Bo AU - Li, Hao AU - Cao, Ying AU - Liu, Bang PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5646 AB - A series of goethite-modified montmorillonite (GMt) materials was synthesized for the amelioration of cationic cadmium (Cd) and anionic arsenic (As) complex contaminants in soil and water bodies. The results showed that goethite (Gt) was successfully loaded onto the surface of montmorillonite (Mt), which possessed more functional groups (such as Fe–O, and Fe–OH) and a larger specific surface area. GMt-0.5 (Mt loaded with Gt at a ratio of 0.5:1) showed the highest adsorption capacity for Cd(II) and As(III) with the maximum of 50.61 mg/g and 57.58 mg/g, respectively. The removal rate of Cd(II) was highly pH dependent, while the removal rate of As(III) showed little dependence on pH. The goethite on montmorillonite might contribute to the formation of surface complexes with As(III) and oxidation of As(III) to As(V). In the binary system, both, synergistic and competitive adsorption existed simultaneously. Importantly, in the binary system, the removal of As(III) was more favorable because of the electrostatic interaction, formation of a ternary complex, and co-precipitation. In addition, the amendment of GMt-0.5 significantly reduced the availability of Cd and As in the soil. This study suggests that GMt-0.5 is a promising candidate for the simultaneous immobilization of metal (loid)s in both, aqueous solution and mine soil. PB - Elsevier B.V. T2 - Journal of Environmental Management T1 - Performance and mechanisms for Cd(II) and As(III) simultaneous adsorption by goethite-loaded montmorillonite in aqueous solution and soil VL - 330 SP - 117163 DO - 10.1016/j.jenvman.2022.117163 ER -
@article{ author = "Zhao, Chenchen and Yao, Jun and Šolević Knudsen, Tatjana and Liu, Jianli and Zhu, Xiaozhe and Ma, Bo and Li, Hao and Cao, Ying and Liu, Bang", year = "2023", abstract = "A series of goethite-modified montmorillonite (GMt) materials was synthesized for the amelioration of cationic cadmium (Cd) and anionic arsenic (As) complex contaminants in soil and water bodies. The results showed that goethite (Gt) was successfully loaded onto the surface of montmorillonite (Mt), which possessed more functional groups (such as Fe–O, and Fe–OH) and a larger specific surface area. GMt-0.5 (Mt loaded with Gt at a ratio of 0.5:1) showed the highest adsorption capacity for Cd(II) and As(III) with the maximum of 50.61 mg/g and 57.58 mg/g, respectively. The removal rate of Cd(II) was highly pH dependent, while the removal rate of As(III) showed little dependence on pH. The goethite on montmorillonite might contribute to the formation of surface complexes with As(III) and oxidation of As(III) to As(V). In the binary system, both, synergistic and competitive adsorption existed simultaneously. Importantly, in the binary system, the removal of As(III) was more favorable because of the electrostatic interaction, formation of a ternary complex, and co-precipitation. In addition, the amendment of GMt-0.5 significantly reduced the availability of Cd and As in the soil. This study suggests that GMt-0.5 is a promising candidate for the simultaneous immobilization of metal (loid)s in both, aqueous solution and mine soil.", publisher = "Elsevier B.V.", journal = "Journal of Environmental Management", title = "Performance and mechanisms for Cd(II) and As(III) simultaneous adsorption by goethite-loaded montmorillonite in aqueous solution and soil", volume = "330", pages = "117163", doi = "10.1016/j.jenvman.2022.117163" }
Zhao, C., Yao, J., Šolević Knudsen, T., Liu, J., Zhu, X., Ma, B., Li, H., Cao, Y.,& Liu, B.. (2023). Performance and mechanisms for Cd(II) and As(III) simultaneous adsorption by goethite-loaded montmorillonite in aqueous solution and soil. in Journal of Environmental Management Elsevier B.V.., 330, 117163. https://doi.org/10.1016/j.jenvman.2022.117163
Zhao C, Yao J, Šolević Knudsen T, Liu J, Zhu X, Ma B, Li H, Cao Y, Liu B. Performance and mechanisms for Cd(II) and As(III) simultaneous adsorption by goethite-loaded montmorillonite in aqueous solution and soil. in Journal of Environmental Management. 2023;330:117163. doi:10.1016/j.jenvman.2022.117163 .
Zhao, Chenchen, Yao, Jun, Šolević Knudsen, Tatjana, Liu, Jianli, Zhu, Xiaozhe, Ma, Bo, Li, Hao, Cao, Ying, Liu, Bang, "Performance and mechanisms for Cd(II) and As(III) simultaneous adsorption by goethite-loaded montmorillonite in aqueous solution and soil" in Journal of Environmental Management, 330 (2023):117163, https://doi.org/10.1016/j.jenvman.2022.117163 . .