Effect of temperature on the electrodeposition of disperse copper deposits
Uticaj temperature na elektrohemijsko taloženje disperznih taloga bakra
dc.creator | Nikolić, Nebojša D. | |
dc.creator | Pavlović, Ljubica | |
dc.creator | Pavlović, Miomir | |
dc.creator | Popov, Konstantin I. | |
dc.date.accessioned | 2019-01-30T17:15:53Z | |
dc.date.available | 2019-01-30T17:15:53Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/331 | |
dc.description.abstract | The effect of temperature on the electrodeposition of copper at overpotentials belonging to the plateau of the limiting diffusion current density and higher was examined by the determination of the average current efficiency of hydrogen evolution and by scanning electron microscopic (SEM) analysis of the morphology of the formed copper deposits. Increasing the temperature of the solution led to a shift of both the beginning and the end of the plateau of the limiting diffusion current density towards lower electrodeposition overpotentials. Also, higher temperatures led to the formation of morphological forms of copper deposits characteristic for electrodeposition of copper at some higher overpotentials. The unexpected trend in the development of copper structures electrodeposited at an overpotential of 800 mV is discussed in terms of the effect of temperature on the viscosity and surface tension of the electroplating solution. | en |
dc.description.abstract | Uticaj temperature na elektrohemijsko taloženje bakra na prenapetostima koje pripadaju platoima granične difuzione gustine struje, kao i na višim prenapetostima je ispitan određivanjem srednjeg iskorišćenja struje reakcije izdvajanja vodonika i analizom morfologija taloga bakra tehnikom skenirajuće elektronske mikroskopije. Povećanje temperature rastvora dovelo je do pomeranja i početka i kraja platoa granične difuzione gustine struje ka nižim prenapetostima. Takođe, povećanje temperature dovelo je do formiranja morfoloških formi taloga bakra karakterističnih za elektrohemijsko taloženje na nekim višim prenapetostima. Neočekivani trend u razvoju struktura bakra dobijenih na prenapetosti od 800 mV je bio diskutovan na osnovu uticaja temperature na viskoznost i površinski napon rastvora za elektrohemijsko taloženje bakra. | sr |
dc.publisher | Serbian Chemical Society | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142032/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | electrodeposition | en |
dc.subject | copper | en |
dc.subject | hydrogen evolution | en |
dc.subject | temperature | en |
dc.subject | viscosity | en |
dc.subject | surface tension | en |
dc.title | Effect of temperature on the electrodeposition of disperse copper deposits | en |
dc.title | Uticaj temperature na elektrohemijsko taloženje disperznih taloga bakra | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Николић, Небојша; Павловић, Миомир; Попов, Константин И.; Павловиц, Љубица Ј.; Утицај температуре на електрохемијско таложење дисперзних талога бакра; Утицај температуре на електрохемијско таложење дисперзних талога бакра; | |
dc.citation.volume | 72 | |
dc.citation.issue | 12 | |
dc.citation.spage | 1369 | |
dc.citation.epage | 1381 | |
dc.citation.other | 72(12): 1369-1381 | |
dc.citation.rank | M23 | |
dc.identifier.doi | 10.2298/JSC0712369N | |
dc.identifier.fulltext | https://cer.ihtm.bg.ac.rs//bitstream/id/9007/329.pdf | |
dc.identifier.scopus | 2-s2.0-36949035155 | |
dc.identifier.wos | 000252412100021 | |
dc.type.version | publishedVersion |