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Reactions with lead tetraacetate. I. Oxidation of saturated aliphatic alcohols. Part 1
(Elsevier, 1963)
It was recently shown that various steroid alcohols could react with lead tetraacetate in non-polar solvents to give tetrahydrofuran and tetrahydropyran derivatives. cyclization occurring when the position of and the ...
Alkylation of carbonyl compounds in the TiCl4-promoted reaction of trimethylsilyl enol ethers with ethylene oxide
(Oxford : Pergamon-Elsevier Science Ltd, 2000)
Titanium tetrachloride promoted reaction of trimethylsilyl enol ethers with ethylene oxide affords homoaldol type products in moderate/good yields. The reaction is believed to proceed via the titanium enolates. (C) 2000 ...
A new type of sesqiterpene lactone isolated from artemisia annua L. arteannuin B
(Elsevier, 1973)
The structure of a new sesquiterpene lactone, arteannuin B, isolated from Artemisia annua L. is reported.
Favorski type rearrangement in the lead tetraacetate oxidation of enamines promoted by boron trifluoride
(Elsevier, 1980)
Favorski type rearrangement has been achieved in the lead tetraacetate oxidation of enamines in the presence of boron trifluoride etherate and alcohol.
X-ray and carbon-13 nuclear magnetic resonance characterization of cyclopropane derivatives obtained by solvolysis of (E)-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates
(Pergamon Press, 1979)
The stereochemistries and conformations of the cyclopropane ring containing compounds derived from (E-3α- and (E)-3β-hydroxy-5,10-seco-1(10)-cholesten-5-one tosylates have been determined by X-ray methods and the results ...
Transannular solvolysis reactions in seco-steroids containing a ten-membered ring.
(Pergamon Press, 1970)
Homoallylic interaction in steroidal cyclodecenyl systems
(Pergamon Press, 1974)
Selective borane reductions of progesterone
(Elsevier, 1967)
A number of selective reductions using borane end metal borohydrides has been described. In our studies of hydroboration of steroid conjugated ketones under different conditions and with different solvents we have found ...
On the choice of optimal conformation in linear free-energy relationships. Reactivity of 2-[(carboxymethyl)sulfanyl]-4-oxo-4-arylbutanoic acids with diphenyldiazomethane
(Amsterdam : Elsevier, 2012)
Rate constants for the esterification of eleven 2-[(carboxymethyl)sulfanyl]-4-oxo-4-arylbutanoic acids
with diphenyldiazomethane in ethanol at 30 C were determined, and correlated with substituent constants
using classical ...
An improved preparation of 3-α-acetoxy-11,20-diketo-(5β)-pregnane, the key intermediate in the synthesis of 11-oxygenated corticosteroids
(Elsevier, 1967)
Although microbiological methods of introducing oxygen at C-11 of the steroid molecule are effective, it is obvious that purely synthetic way of producing cortisone and its analogs from bile acids or hecogenin have never ...