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Electrocatalysis by foreign metal monolayers. Oxidation of formic acid on palladium
(Elsevier, 1978)
Catalytic effects of foreign metal monolayers deposited at underpotentials have been found for the oxidation of formic acid on palladium electrode. Palladium is known to form no poisoning species in oxidation of HCOOH. ...
An analysis of elementary processes of water desorption from zeolites of type a Part II. Zeolites with bivalent counterions
(Elsevier, 1976)
DSC and EGA were used to follow the process of water desorption from synthetic MgA, ZnA and CdA zeolites. Applying a semi-empirical algorithm the complex experimental curves were resolved into elementary ones. It turned ...
On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media
(Elsevier, 1977)
The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange ...
Kinetics and mechanism of deposition of zinc from zincate in concentrated alkali hydroxide solutions
(Elsevier, 1976)
Galvanostatic investigation has been carried out of the kinetics of the reaction on zinc amalgam hanging mercury drop immersed in alkaline zincate solutions at KOH concentrations ranging from 1 to 14 normal. Three kinds ...
Inhibitory effects of manganeous, cadmium and zinc ions on hydrogen evolution reaction and corrosion of iron in sulphuric acid solutions
(Pergamon Press, 1978)
The presence of metal ions (Cd2+, Mn2+, Zn2+), more electronegative than the cathodic potential for the hydrogen evolution reaction on iron in a 0.25M H2SO4 solution, inhibits the hydrogen evolution reaction and corrosion ...
Multiphoton resonance absorption characteristics
(IOP Publishing, 1977)
It is shown that the Dyson equation gives finite values for multiphoton resonance absorption rates when an appropriate diagram summation technique is applied. A simple recurrence formula connects the n-photon absorption ...
Studies of the deposition of cadmium on foreign substrates
(Elsevier, 1977)
Cadmium deposition on nickel, lead, silver, gold and copper has been studied by the potential sweep and potentiostatic method with a simultaneous observation of the surface by optical microscopy. It was found that the ...
Control of intramolecular γ-alkylation vs. α-alkylation of an αβ-unsaturated ketone: An unusual solvent effect
(Royal Society of Chemistry, 1979)
Most base-solvent combinations convert (2) into (3); γ-alkylation to yield (5) is effected by sodium hydroxide in dimethyl sulphoxide-water mixtures in which the water content is critical.
Individual ionic activities and mass transfer in anodic chlorate formation
(Switzerland : Springer Nature, 1973)
The individual activity of hypochlorite ion in concentrated neutral salt (NaCl-NaClO3) solutions has been estimated kinetically by measurement of the Faradaic efficiency in a chlorate producing system comprised of a cell ...
Synthesis and solution properties of poly(diphenyl itaconate)
(Elsevier, 1976)
Solid diphenyl itaconate monomer was obtained by esterification in the presence of diphosphorus pentoxide and polymerized in bulk with AIBN as initiator. The non-film forming polymer powder was characterized by fractionation, ...