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Structural effects in electrocatalysis. Oxygen reduction on the Au (100) single crystal electrode
(Elsevier, 1984)
The kinetics of O2 reduction on the Au (100) single crystal electrode have been examined in alkaline electrolytes using the rotating dise method. A comparison has been made with the Au (110) and Au (111) surfaces. The ...
Electrocatalytic optimization of faradaic yields in the chlorate cell process
(Elsevier, 1984)
It has been shown that while the mixed RuO2TiO2 coated titanium anode deteriorates very quickly in the presence of ionic phosphate species, the electrode containing palladium and tin oxides in the coating mixture as well ...
Electrocatalysis of oxygen on single crystal gold electrodes
(Elsevier, 1989)
Oxide formation and oxygen reduction on gold have been investigated with single crystal electrode surfaces of various orientations. Both reactions show sensitivity to the surface orientation, presence of steps, their density ...
Oxide formation on gold single crystal stepped surfaces
(Elsevier, 1988)
Oxide formation and anion adsorption have been studied on gold single crystal stepped surfaces. Most of the measurements were performed in sulphuric and some in perchloric acid solutions by cyclic voltammetry and by double ...
Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces
(Elsevier, 1984)
The electrocrystallization of thin anodic films on metal electrodes continues
provoke interest since the original work of Bewick et al. [1]. These
studies have been focused on the film formation on mercury [1--3] ...
Photoelectrochemical microscopy of oxide films on metals: Ti/TiO2 interface
(Elsevier, 1988)
Thin electrochemically grown oxide films on polycrystalline titanium substrates were examined by photoelectrochemical and electron diffraction techniques. Photoelectrochemical microscopy, based on illumination by a focused ...
The surface structure of RuO2: A leed, auger and XPS study of the (110) and (100) faces
(Elsevier, 1988)
The (110) and the (100) surfaces of RuO2 show well defined LEED patterns. The surface lattice dimensions agree within 5% with the values predicted from X-ray diffraction. Both surfaces undergo a series of reversible surface ...
Oxygen reduction on a ruthenium electrode in acid electrolytes
(Elsevier, 1986)
The kinetics and mechanism of O2 reduction on an Ru electrode in acid electrolytes have been measured by using a disc—ring method. The reaction proceeds through a “parallel” mechanism with the exchange of approximately ...
Anodic deposition of colloidal gold
(Elsevier, 1984)
Colloidal gold solutions were prepared following classical recipes. When electrolysed between graphite electrodes, gold was found to deposit at the anode. The rate of deposition was dependent on the anode potential, on the ...
The Reductive Conversion of Some Cyclic and Acyclic vic-Epoxides to Alcohols by Means of Lithium Aluminium Hydride/Aluminium Trichloride
(Wiley, 1985)
Unsubstituted medium‐ring 1,2‐epoxycycloalkanes and certain vic‐epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAlH4 alone is used as reducing agent. However, the combination of LiAlH4 and AlCl3, ...