dc.creator | Čobeljić, Božidar | |
dc.creator | Warzajtis, Beata | |
dc.creator | Rychlewska, Urszula | |
dc.creator | Radanović, Dušanka | |
dc.creator | Spasojević, Vojislav | |
dc.creator | Sladić, Dušan | |
dc.creator | Eshkourfu, Rabia | |
dc.creator | Anđelković, Katarina | |
dc.date.accessioned | 2019-01-30T17:31:09Z | |
dc.date.available | 2019-01-30T17:31:09Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 0095-8972 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/1041 | |
dc.description.abstract | A new malonic dihydrazide-based ligand, N',N'(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide (H(2)L3), has been prepared and characterized by elemental analysis, IR, C-13 NMR, and H-1 NMR spectroscopies. In the reaction of H(2)L3 with Ni(II) a binuclear complex has been obtained. The structure of the complex was established by X-ray analysis. Each Ni(II) is coordinated with two NNO donor sets from two ligand molecules in dianionic form (L3(2-)) forming an octahedral geometry. Multiple intramolecular C-H center dot center dot center dot pi (chelate ring) interactions support the molecular geometry of the [Ni-2(L3)(2)] complex. The structure of [Ni-2(L3)(2)] is compared with those of analogous Ni(II) complexes with pyridine dihydrazone type ligands. Magnetic behavior of the dinuclear complex was studied in temperature range of 2-300 K. | en |
dc.publisher | Taylor & Francis Ltd, Abingdon | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS// | |
dc.rights | restrictedAccess | |
dc.source | Journal of Coordination Chemistry | |
dc.subject | Ni(II) complexes | en |
dc.subject | X-ray structure | en |
dc.subject | Intramolecular interactions | en |
dc.title | Synthesis and structure of a Ni(II) complex with N ',N '(2)-bis[(1E)-1-(2-quinolyl)methylene]propanedihydrazide: multiple intramolecular CH center dot center dot center dot pi interactions between quinoline and quinolineimine chelate | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Сладиц, Дусан; Цобељиц, Бозидар; Есхкоурфу, Рабиа; Спасојевиц, Војислав; Радановић, Душанка; Рyцхлеwска, Урсзула; Wарзајтис, Беата; Aнђелковиц, Катарина; | |
dc.citation.volume | 65 | |
dc.citation.issue | 4 | |
dc.citation.spage | 655 | |
dc.citation.epage | 667 | |
dc.citation.other | 65(4): 655-667 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.1080/00958972.2012.658778 | |
dc.identifier.scopus | 2-s2.0-84861554734 | |
dc.identifier.wos | 000302036000008 | |
dc.type.version | publishedVersion | |