Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups
Samo za registrovane korisnike
2012
Autori
Filipovic, NenadTodorović, Tamara
Radanović, Dušanka
Divjakovic, Vladimir
Marković, Rade
Pajic, Ivana
Anđelković, Katarina
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia
Ključne reči:
Cd(II) complexes / N-Heteroaromatic hydrazones / X-ray analysis / NMR spectroscopy / Biological activityIzvor:
Polyhedron, 2012, 31, 1, 19-28Izdavač:
- Oxford : Pergamon-Elsevier Science Ltd
Finansiranje / projekti:
- Interakcije prirodnih proizvoda, njihovih derivata i kompleksnih jedinjenja sa proteinima i nukleinskim kiselinama (RS-MESTD-Basic Research (BR or ON)-172055)
DOI: 10.1016/j.poly.2011.07.023
ISSN: 0277-5387
WoS: 000300642900003
Scopus: 2-s2.0-84155163213
Institucija/grupa
IHTMTY - JOUR AU - Filipovic, Nenad AU - Todorović, Tamara AU - Radanović, Dušanka AU - Divjakovic, Vladimir AU - Marković, Rade AU - Pajic, Ivana AU - Anđelković, Katarina PY - 2012 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/994 AB - Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia PB - Oxford : Pergamon-Elsevier Science Ltd T2 - Polyhedron T1 - Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups VL - 31 IS - 1 SP - 19 EP - 28 DO - 10.1016/j.poly.2011.07.023 ER -
@article{ author = "Filipovic, Nenad and Todorović, Tamara and Radanović, Dušanka and Divjakovic, Vladimir and Marković, Rade and Pajic, Ivana and Anđelković, Katarina", year = "2012", abstract = "Two novel cadmium(II) complexes with condensation derivatives of 2-acetylpyridine or 2,6-diacetylpyridine with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of the complexes revealed a bidentate coordination of the 2-acetylpyridine derivative, while the symmetric 2,6-diacetylpyridine derivative was coordinated tridentately. It was found that the oxygen atoms were not coordinated to the cadmium ions, despite the fact that they are the position to form six membered chelate rings. NMR spectroscopy investigations showed that the coordination properties of the ligands do not change in solution. Both complexes possess cytotoxic potential, as determined by the toxicity test to Artemia", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "Polyhedron", title = "Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups", volume = "31", number = "1", pages = "19-28", doi = "10.1016/j.poly.2011.07.023" }
Filipovic, N., Todorović, T., Radanović, D., Divjakovic, V., Marković, R., Pajic, I.,& Anđelković, K.. (2012). Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups. in Polyhedron Oxford : Pergamon-Elsevier Science Ltd., 31(1), 19-28. https://doi.org/10.1016/j.poly.2011.07.023
Filipovic N, Todorović T, Radanović D, Divjakovic V, Marković R, Pajic I, Anđelković K. Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups. in Polyhedron. 2012;31(1):19-28. doi:10.1016/j.poly.2011.07.023 .
Filipovic, Nenad, Todorović, Tamara, Radanović, Dušanka, Divjakovic, Vladimir, Marković, Rade, Pajic, Ivana, Anđelković, Katarina, "Solid state and solution structures of Cd(II) complexes with two N-heteroaromatic Schiff bases containing ester groups" in Polyhedron, 31, no. 1 (2012):19-28, https://doi.org/10.1016/j.poly.2011.07.023 . .