Electrochemical Examination of Copper(II) Complexes with Octaazamacrocyclic Ligand and Heterocyclic Dithiocarbamate
Samo za registrovane korisnike
2012
Autori
Petković, Branka B.Stevanović, Sanja
Budimir, Milana V.
Sovilj, Sofija P.
Jovanović, Vladislava M.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Mixed ligand dinuclear copper(II) complexes of the general formula [Cu2(Rdtc)tpmc)](ClO4)3 with octaazamacrocyclic ligand tpmc and four different heterocyclic dithiocarbamate ligands Rdtc-, as well as the complexes [Cu2(tpmc)](ClO4)4 and [Cu(tpmc)](ClO4)2 center dot 2H2O were studied in aqueous NaClO4 and HClO4 solutions by cyclic voltammetry on glassy carbon electrode. The electrochemical properties of the ligands and Cu(II) complexes were correlated with their electronic structure. Conductometric experiments showed different stoichiometry in complexation of tpmc with Cu2+ ions and transport of ions in acetonitrile and in aqueous media. These studies clarified the application of this macrocyclic ligand as ionophore in a PVC membrane copper(II) selective electrode and contributed elucidation of its sensor properties.
Ključne reči:
Copper(II) complexes / Cyclic voltammetry / tpmc ligands / Conductometry / Cu(II) sensorsIzvor:
Electroanalysis, 2012, 24, 7, 1605-1612Izdavač:
- Wiley-Blackwell, Malden
Finansiranje / projekti:
DOI: 10.1002/elan.201200120
ISSN: 1040-0397
WoS: 000305999200016
Scopus: 2-s2.0-84863548644
Institucija/grupa
IHTMTY - JOUR AU - Petković, Branka B. AU - Stevanović, Sanja AU - Budimir, Milana V. AU - Sovilj, Sofija P. AU - Jovanović, Vladislava M. PY - 2012 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/973 AB - Mixed ligand dinuclear copper(II) complexes of the general formula [Cu2(Rdtc)tpmc)](ClO4)3 with octaazamacrocyclic ligand tpmc and four different heterocyclic dithiocarbamate ligands Rdtc-, as well as the complexes [Cu2(tpmc)](ClO4)4 and [Cu(tpmc)](ClO4)2 center dot 2H2O were studied in aqueous NaClO4 and HClO4 solutions by cyclic voltammetry on glassy carbon electrode. The electrochemical properties of the ligands and Cu(II) complexes were correlated with their electronic structure. Conductometric experiments showed different stoichiometry in complexation of tpmc with Cu2+ ions and transport of ions in acetonitrile and in aqueous media. These studies clarified the application of this macrocyclic ligand as ionophore in a PVC membrane copper(II) selective electrode and contributed elucidation of its sensor properties. PB - Wiley-Blackwell, Malden T2 - Electroanalysis T1 - Electrochemical Examination of Copper(II) Complexes with Octaazamacrocyclic Ligand and Heterocyclic Dithiocarbamate VL - 24 IS - 7 SP - 1605 EP - 1612 DO - 10.1002/elan.201200120 ER -
@article{ author = "Petković, Branka B. and Stevanović, Sanja and Budimir, Milana V. and Sovilj, Sofija P. and Jovanović, Vladislava M.", year = "2012", abstract = "Mixed ligand dinuclear copper(II) complexes of the general formula [Cu2(Rdtc)tpmc)](ClO4)3 with octaazamacrocyclic ligand tpmc and four different heterocyclic dithiocarbamate ligands Rdtc-, as well as the complexes [Cu2(tpmc)](ClO4)4 and [Cu(tpmc)](ClO4)2 center dot 2H2O were studied in aqueous NaClO4 and HClO4 solutions by cyclic voltammetry on glassy carbon electrode. The electrochemical properties of the ligands and Cu(II) complexes were correlated with their electronic structure. Conductometric experiments showed different stoichiometry in complexation of tpmc with Cu2+ ions and transport of ions in acetonitrile and in aqueous media. These studies clarified the application of this macrocyclic ligand as ionophore in a PVC membrane copper(II) selective electrode and contributed elucidation of its sensor properties.", publisher = "Wiley-Blackwell, Malden", journal = "Electroanalysis", title = "Electrochemical Examination of Copper(II) Complexes with Octaazamacrocyclic Ligand and Heterocyclic Dithiocarbamate", volume = "24", number = "7", pages = "1605-1612", doi = "10.1002/elan.201200120" }
Petković, B. B., Stevanović, S., Budimir, M. V., Sovilj, S. P.,& Jovanović, V. M.. (2012). Electrochemical Examination of Copper(II) Complexes with Octaazamacrocyclic Ligand and Heterocyclic Dithiocarbamate. in Electroanalysis Wiley-Blackwell, Malden., 24(7), 1605-1612. https://doi.org/10.1002/elan.201200120
Petković BB, Stevanović S, Budimir MV, Sovilj SP, Jovanović VM. Electrochemical Examination of Copper(II) Complexes with Octaazamacrocyclic Ligand and Heterocyclic Dithiocarbamate. in Electroanalysis. 2012;24(7):1605-1612. doi:10.1002/elan.201200120 .
Petković, Branka B., Stevanović, Sanja, Budimir, Milana V., Sovilj, Sofija P., Jovanović, Vladislava M., "Electrochemical Examination of Copper(II) Complexes with Octaazamacrocyclic Ligand and Heterocyclic Dithiocarbamate" in Electroanalysis, 24, no. 7 (2012):1605-1612, https://doi.org/10.1002/elan.201200120 . .