Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey"
Аутори
Jevtović, MimaPevec, Andrej
Turel, Iztok
Radanović, Dušanka
Milčić, Miloš
Gruden, Maja
Zlatar, Matija
Mitić, Dragana
Anđelković, Katarina
Čobeljić, Božidar
Скуп података (Објављена верзија)
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Приказ свих података о документуАпстракт
In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions.
1. Experimental section.
2. Single crystal X-ray diffraction study.
3. Computational details.
4. Additional details
Кључне речи:
Schiff base ligands / nickel(II) / nickel(III) / complexes / synthesis / X-ray structure / DFT / syngle crystal / EPRИзвор:
Inorganic Chemistry Communications, 2023Издавач:
- Elsevier
Финансирање / пројекти:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-MESTD-inst-2020-200168)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200288 (Иновациони центар Хемијског факултета у Београду доо) (RS-MESTD-inst-2020-200288)
- Slovenian Research Agency (ARRS), grant number P1-0175
Напомена:
- The accepted, peer-reviewed version of the manuscript: https://cer.ihtm.bg.ac.rs/handle/123456789/6766
- Published version of the manuscript: https://cer.ihtm.bg.ac.rs/handle/123456789/6788
- This is supporting information for: Jevtović, Mima, Pevec, Andrej, Turel, Iztok, Radanović, Dušanka, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Mitić, Dragana, Anđelković, Katarina, Čobeljić, Božidar, "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey" in Inorganic Chemistry Communications, 158 (2023):111582, https://doi.org/10.1016/j.inoche.2023.111582
Повезане информације:
- Повезани садржај
https://cer.ihtm.bg.ac.rs/handle/123456789/6788 - Повезани садржај
http://dx.doi.org/10.1016/j.inoche.2023.111582 - Повезани садржај
https://cer.ihtm.bg.ac.rs/handle/123456789/6766
Колекције
Институција/група
IHTMTY - DATA AU - Jevtović, Mima AU - Pevec, Andrej AU - Turel, Iztok AU - Radanović, Dušanka AU - Milčić, Miloš AU - Gruden, Maja AU - Zlatar, Matija AU - Mitić, Dragana AU - Anđelković, Katarina AU - Čobeljić, Božidar PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6788 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/7529 AB - In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions. AB - 1. Experimental section. 2. Single crystal X-ray diffraction study. 3. Computational details. 4. Additional details PB - Elsevier T2 - Inorganic Chemistry Communications T1 - Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey" UR - https://hdl.handle.net/21.15107/rcub_cer_7529 ER -
@misc{ author = "Jevtović, Mima and Pevec, Andrej and Turel, Iztok and Radanović, Dušanka and Milčić, Miloš and Gruden, Maja and Zlatar, Matija and Mitić, Dragana and Anđelković, Katarina and Čobeljić, Božidar", year = "2023", abstract = "In this paper, we report the synthesis, characterization, and X-ray structure analysis of one octahedral Ni(II) complex, [Ni(HL1 )2](BF4)2*H2O, formed by coordination of two ligands with NNS donor atom sets (HL1 ligand, (E)-2-(1-(thiazol-2-yl)ethylidene)hydrazine-1-carbothioamide), and Ni(III) complex, [Ni(L2 )(N3)3], formed by coordination of one hydrazone ligand coordinated through NNO donor set and three azide anions (HL2Cl ligand, (E)−1-(2-oxo-2-(2-(1-(pyridin-2- yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium chloride), complemented by DFT calculations. To the best of our knowledge this is the first Ni(III) complex obtained under ambient conditions., 1. Experimental section. 2. Single crystal X-ray diffraction study. 3. Computational details. 4. Additional details", publisher = "Elsevier", journal = "Inorganic Chemistry Communications", title = "Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey"", url = "https://hdl.handle.net/21.15107/rcub_cer_7529" }
Jevtović, M., Pevec, A., Turel, I., Radanović, D., Milčić, M., Gruden, M., Zlatar, M., Mitić, D., Anđelković, K.,& Čobeljić, B.. (2023). Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey". in Inorganic Chemistry Communications Elsevier.. https://hdl.handle.net/21.15107/rcub_cer_7529
Jevtović M, Pevec A, Turel I, Radanović D, Milčić M, Gruden M, Zlatar M, Mitić D, Anđelković K, Čobeljić B. Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey". in Inorganic Chemistry Communications. 2023;. https://hdl.handle.net/21.15107/rcub_cer_7529 .
Jevtović, Mima, Pevec, Andrej, Turel, Iztok, Radanović, Dušanka, Milčić, Miloš, Gruden, Maja, Zlatar, Matija, Mitić, Dragana, Anđelković, Katarina, Čobeljić, Božidar, "Supporting Information for: "Nickel(II) and nickel(III) Thiosemicarbazone and Hydrazone Complexes: An Unexpected Journey"" in Inorganic Chemistry Communications (2023), https://hdl.handle.net/21.15107/rcub_cer_7529 .