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Supplementary material to: "Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity"
dc.creator | Vitomirov, Teodora | |
dc.creator | Čobeljić, Božidar | |
dc.creator | Pevec, Andrej | |
dc.creator | Radanović, Dušanka | |
dc.creator | Novaković, Irena | |
dc.creator | Savić, Milica | |
dc.creator | Anđelković, Katarina | |
dc.creator | Šumar-Ristović, Maja | |
dc.date.accessioned | 2024-03-22T14:09:17Z | |
dc.date.available | 2024-03-22T14:09:17Z | |
dc.date.issued | 2023 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/7528 | |
dc.description.abstract | The condensation product of 7-acetyl-6-azaindole and Girard's T reagent ((E)-2-(2-(1-(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-m-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center. This end-to-end (di-m-1,3-N3) azide bridge binding mode has not yet occurred in Cu(II) complexes containing the NNO-donor hydrazone ligands, which makes the structure of the complex even more interesting for further studies. The complex was characterized by elemental analysis, IR spectroscopy and X-ray crystallography, and it was found that it crystallizes in the triclinic space group P–1 with the asymmetric unit comprising one Cu(II) centre, zwitterionic ligand L, one azide (N3−) ligand, and BF4− counter anion. Examination of antimicrobial activity of the complex shows higher antifungal and antibacterial activity towards tested Gram-positive bacteria in comparison to the hydrazone ligand, with the antifungal activity of the complex even being comparable to the activity of amphotericin B. | |
dc.publisher | Serbian Chemical Society | en |
dc.relation | info:eu-repo/grantAgreement/ScienceFundRS/Ideje/7750288/RS// | en |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200168/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/inst-2020/200288/RS// | |
dc.relation | Slovenian Research Agency (ARRS), grant number P1-0175 | |
dc.relation.isreferencedby | https://cer.ihtm.bg.ac.rs/handle/123456789/7320 | |
dc.relation.isreferencedby | https://cer.ihtm.bg.ac.rs/handle/123456789/6435 | |
dc.relation.isreferencedby | https://doi.org/10.2298/JSC230623044V | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject | Girard's T reagent | |
dc.subject | X-ray crystallography | |
dc.subject | antibacterial activity | |
dc.subject | antifungal activity | |
dc.subject | dinuclear complexes | |
dc.subject | azide bridges | |
dc.subject | Cu(II) | |
dc.title | Supplementary material to: "Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity" | en |
dc.type | dataset | en |
dc.rights.license | BY-NC-ND | |
dc.description.other | Accepted version of the manuscript: [https://cer.ihtm.bg.ac.rs/handle/123456789/6435] | |
dc.description.other | Published version of the manuscript: [https://cer.ihtm.bg.ac.rs/handle/123456789/7320] | |
dc.description.other | Supplementary material for: Vitomirov, Teodora, Čobeljić, Božidar, Pevec, Andrej, Radanović, Dušanka, Novaković, Irena, Savić, Milica, Anđelković, Katarina, Šumar-Ristović, Maja, "Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity" in Journal of the Serbian Chemical Society, 88, no. 9 (2023):877-888, [https://doi.org/10.2298/JSC230623044V] | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_cer_7528 | |
dc.identifier.fulltext | http://cer.ihtm.bg.ac.rs/bitstream/id/29995/jscssi_x1.pdf | |
dc.type.version | publishedVersion |
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Istraživački podaci / Research data
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TMMagCat
Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes