On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media
Abstract
The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange current density, as also the α value, ks, and the partial reaction order of each of the component which takes place in the reaction, have been determined on the grounds of different kind of anions in the solution. The two-step single-electron exchange mechanism has been suggested, as also the one-step exchange reaction in combination with the reaction of disproportionation.
Keywords:
Cadmium and alloys / electron / kinetics / galvanostatic single-pulse methodSource:
Electrochimica Acta, 1977, 22, 3, 233-236Publisher:
- Elsevier
Collections
Institution/Community
IHTMTY - JOUR AU - Jovanović, D.R. AU - Rakić, T. PY - 1977 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4536 AB - The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange current density, as also the α value, ks, and the partial reaction order of each of the component which takes place in the reaction, have been determined on the grounds of different kind of anions in the solution. The two-step single-electron exchange mechanism has been suggested, as also the one-step exchange reaction in combination with the reaction of disproportionation. PB - Elsevier T2 - Electrochimica Acta T1 - On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media VL - 22 IS - 3 SP - 233 EP - 236 DO - 10.1016/0013-4686(77)85066-4 ER -
@article{ author = "Jovanović, D.R. and Rakić, T.", year = "1977", abstract = "The kinetics and mechanism have been investigated in the Cd(II)/Cd(Hg) system in 2 M NaClO4 + 1 M HClO4, at 25 ± 0.5°C. The galvanostatic single-pulse method has been used. The value of double-layer capacity, exchange current density, as also the α value, ks, and the partial reaction order of each of the component which takes place in the reaction, have been determined on the grounds of different kind of anions in the solution. The two-step single-electron exchange mechanism has been suggested, as also the one-step exchange reaction in combination with the reaction of disproportionation.", publisher = "Elsevier", journal = "Electrochimica Acta", title = "On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media", volume = "22", number = "3", pages = "233-236", doi = "10.1016/0013-4686(77)85066-4" }
Jovanović, D.R.,& Rakić, T.. (1977). On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media. in Electrochimica Acta Elsevier., 22(3), 233-236. https://doi.org/10.1016/0013-4686(77)85066-4
Jovanović D, Rakić T. On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media. in Electrochimica Acta. 1977;22(3):233-236. doi:10.1016/0013-4686(77)85066-4 .
Jovanović, D.R., Rakić, T., "On the kinetics and mechanism of the Cd(II)/Cd(Hg) system in acid media" in Electrochimica Acta, 22, no. 3 (1977):233-236, https://doi.org/10.1016/0013-4686(77)85066-4 . .