Deuterium‐induced 13C nuclear magnetic resonance isotope shifts and 13C-2H couplings for signal assignments and determination of deuteration site in cyclooctanone
Abstract
Unambiguous signal assignments in the 13C spectra of monodeuterated cyclooctanones derived from the lead tetraacetate or silver oxide/bromine oxidations of the corresponding 1‐monodeutero‐alcohols have been obtained from deuterium‐induced 13C isotope shifts and geminal and vicinal 13C-2H spin‐spin coupling constants. The label in the ketones is shown to be in position 5.
Keywords:
isotope / magnetic resonance / 13C NMR / cyclooctanones / spin‐spin coupling / NMR spectrometrySource:
Organic Magnetic Resonance, 1981, 17, 4, 299-300Publisher:
- Wiley
Funding / projects:
- The Research Fund of SR Serbia, Yugoslavia
DOI: 10.1002/mrc.1270170415
ISSN: 0030-4921; 1097-458X
Scopus: 2-s2.0-84986745927
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Institution/Community
IHTMTY - JOUR AU - Milosavljević, Slobodan AU - Jeremić, Dragoslav AU - Mihailović, Milhailo Lj. AU - Wehrli, Felix W. PY - 1981 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4421 AB - Unambiguous signal assignments in the 13C spectra of monodeuterated cyclooctanones derived from the lead tetraacetate or silver oxide/bromine oxidations of the corresponding 1‐monodeutero‐alcohols have been obtained from deuterium‐induced 13C isotope shifts and geminal and vicinal 13C-2H spin‐spin coupling constants. The label in the ketones is shown to be in position 5. PB - Wiley T2 - Organic Magnetic Resonance T1 - Deuterium‐induced 13C nuclear magnetic resonance isotope shifts and 13C-2H couplings for signal assignments and determination of deuteration site in cyclooctanone VL - 17 IS - 4 SP - 299 EP - 300 DO - 10.1002/mrc.1270170415 ER -
@article{ author = "Milosavljević, Slobodan and Jeremić, Dragoslav and Mihailović, Milhailo Lj. and Wehrli, Felix W.", year = "1981", abstract = "Unambiguous signal assignments in the 13C spectra of monodeuterated cyclooctanones derived from the lead tetraacetate or silver oxide/bromine oxidations of the corresponding 1‐monodeutero‐alcohols have been obtained from deuterium‐induced 13C isotope shifts and geminal and vicinal 13C-2H spin‐spin coupling constants. The label in the ketones is shown to be in position 5.", publisher = "Wiley", journal = "Organic Magnetic Resonance", title = "Deuterium‐induced 13C nuclear magnetic resonance isotope shifts and 13C-2H couplings for signal assignments and determination of deuteration site in cyclooctanone", volume = "17", number = "4", pages = "299-300", doi = "10.1002/mrc.1270170415" }
Milosavljević, S., Jeremić, D., Mihailović, M. Lj.,& Wehrli, F. W.. (1981). Deuterium‐induced 13C nuclear magnetic resonance isotope shifts and 13C-2H couplings for signal assignments and determination of deuteration site in cyclooctanone. in Organic Magnetic Resonance Wiley., 17(4), 299-300. https://doi.org/10.1002/mrc.1270170415
Milosavljević S, Jeremić D, Mihailović ML, Wehrli FW. Deuterium‐induced 13C nuclear magnetic resonance isotope shifts and 13C-2H couplings for signal assignments and determination of deuteration site in cyclooctanone. in Organic Magnetic Resonance. 1981;17(4):299-300. doi:10.1002/mrc.1270170415 .
Milosavljević, Slobodan, Jeremić, Dragoslav, Mihailović, Milhailo Lj., Wehrli, Felix W., "Deuterium‐induced 13C nuclear magnetic resonance isotope shifts and 13C-2H couplings for signal assignments and determination of deuteration site in cyclooctanone" in Organic Magnetic Resonance, 17, no. 4 (1981):299-300, https://doi.org/10.1002/mrc.1270170415 . .