Inhibition of the anodic dissolution of iron in alkaline solution by metal complex ions
Abstract
The possible inhibiting effects of GaO33-, GeO32-, CrO32-, and MoO42- ions on anodic and cathodic reactions on iron in 5 M KOH were studied. It was shown that a concentration of these ions of 10-3 M inhibits the anodic iron dissolution reaction 2-3 times, while no effect on the hydrogen evolution reaction was observed. The effect was explained by the underpotential deposition of adatoms of the metal complexing ions on the iron electrode.
Keywords:
alkaline solution / ions / iron electrodeSource:
Corrosion Science, 1983, 23, 7, 683-686Publisher:
- Elsevier
Funding / projects:
- The Research Fund of Serbia
Collections
Institution/Community
IHTMTY - JOUR AU - Dražić, Dragutin M. AU - Chen, Shen Hao PY - 1983 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4411 AB - The possible inhibiting effects of GaO33-, GeO32-, CrO32-, and MoO42- ions on anodic and cathodic reactions on iron in 5 M KOH were studied. It was shown that a concentration of these ions of 10-3 M inhibits the anodic iron dissolution reaction 2-3 times, while no effect on the hydrogen evolution reaction was observed. The effect was explained by the underpotential deposition of adatoms of the metal complexing ions on the iron electrode. PB - Elsevier T2 - Corrosion Science T1 - Inhibition of the anodic dissolution of iron in alkaline solution by metal complex ions VL - 23 IS - 7 SP - 683 EP - 686 DO - 10.1016/0010-938X(83)90032-X ER -
@article{ author = "Dražić, Dragutin M. and Chen, Shen Hao", year = "1983", abstract = "The possible inhibiting effects of GaO33-, GeO32-, CrO32-, and MoO42- ions on anodic and cathodic reactions on iron in 5 M KOH were studied. It was shown that a concentration of these ions of 10-3 M inhibits the anodic iron dissolution reaction 2-3 times, while no effect on the hydrogen evolution reaction was observed. The effect was explained by the underpotential deposition of adatoms of the metal complexing ions on the iron electrode.", publisher = "Elsevier", journal = "Corrosion Science", title = "Inhibition of the anodic dissolution of iron in alkaline solution by metal complex ions", volume = "23", number = "7", pages = "683-686", doi = "10.1016/0010-938X(83)90032-X" }
Dražić, D. M.,& Chen, S. H.. (1983). Inhibition of the anodic dissolution of iron in alkaline solution by metal complex ions. in Corrosion Science Elsevier., 23(7), 683-686. https://doi.org/10.1016/0010-938X(83)90032-X
Dražić DM, Chen SH. Inhibition of the anodic dissolution of iron in alkaline solution by metal complex ions. in Corrosion Science. 1983;23(7):683-686. doi:10.1016/0010-938X(83)90032-X .
Dražić, Dragutin M., Chen, Shen Hao, "Inhibition of the anodic dissolution of iron in alkaline solution by metal complex ions" in Corrosion Science, 23, no. 7 (1983):683-686, https://doi.org/10.1016/0010-938X(83)90032-X . .