Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids
Само за регистроване кориснике
1966
Аутори
Mihailović, Milhailo Lj.Lorenc, Ljubinka
Gašić, Miroslav J.
Rogić, Milorad
Melera, A.
Stefanović, Milutin
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied and, as expected from conformational analysis, it was found that only the trans-isomer readily undergoes transannular cyclizations
Кључне речи:
cis-trans / isomerisation / steroids / configuration / NMR spectrometry / Conformational Analysis / transannular cyclizationsИзвор:
Tetrahedron, 1966, 22, 7, 2345-2358Издавач:
- Elsevier
Институција/група
IHTMTY - JOUR AU - Mihailović, Milhailo Lj. AU - Lorenc, Ljubinka AU - Gašić, Miroslav J. AU - Rogić, Milorad AU - Melera, A. AU - Stefanović, Milutin PY - 1966 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4161 AB - Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied and, as expected from conformational analysis, it was found that only the trans-isomer readily undergoes transannular cyclizations PB - Elsevier T2 - Tetrahedron T1 - Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids VL - 22 IS - 7 SP - 2345 EP - 2358 DO - 10.1016/S0040-4020(01)82154-2 ER -
@article{ author = "Mihailović, Milhailo Lj. and Lorenc, Ljubinka and Gašić, Miroslav J. and Rogić, Milorad and Melera, A. and Stefanović, Milutin", year = "1966", abstract = "Assignment of configuration to the 1,10-double bond in the cis-trans isomeric 3β-acetoxy-5,10-seco-1,10-cholesten-5-ones has been achieved by means of NMR spectrometry. Some reactions of these new compounds have been studied and, as expected from conformational analysis, it was found that only the trans-isomer readily undergoes transannular cyclizations", publisher = "Elsevier", journal = "Tetrahedron", title = "Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids", volume = "22", number = "7", pages = "2345-2358", doi = "10.1016/S0040-4020(01)82154-2" }
Mihailović, M. Lj., Lorenc, L., Gašić, M. J., Rogić, M., Melera, A.,& Stefanović, M.. (1966). Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids. in Tetrahedron Elsevier., 22(7), 2345-2358. https://doi.org/10.1016/S0040-4020(01)82154-2
Mihailović ML, Lorenc L, Gašić MJ, Rogić M, Melera A, Stefanović M. Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids. in Tetrahedron. 1966;22(7):2345-2358. doi:10.1016/S0040-4020(01)82154-2 .
Mihailović, Milhailo Lj., Lorenc, Ljubinka, Gašić, Miroslav J., Rogić, Milorad, Melera, A., Stefanović, Milutin, "Configuration and reactivity of ten-membered 5,10-seco-compounds obtained by fragmentation of 5-hydroxy-steroids" in Tetrahedron, 22, no. 7 (1966):2345-2358, https://doi.org/10.1016/S0040-4020(01)82154-2 . .