Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands
Samo za registrovane korisnike
2007
Autori
Filipović, N.R.Todorović, Tamara
Sladić, Dušan
Novaković, Irena
Jeremić, D. A.
Anđelković, Katarina
Konferencijski prilog (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
New complexes of Pt(II) with condensation derivatives of ethyl hydrazinoacetate and either 2-acetylpyridine or 2-quinolinecarboxaldehyde, and of Pd(II) with the condensation derivative of ethyl hydrazinoacetate and 2-quinolinecarboxaldehyde were synthesized and characterized by elemental analysis, IR, 1H- and 13C-NMR spectroscopy, and molar conductivity measurements. The complexes have a square planar geometry, ligands binding as bidentates in the neutral form, and the remaining two coordination sites being occupied by chloride ions. Biological activity of new complexes, and of previously synthesized Pd(II), Cd(II), Co(III) and Zn(II) complexes with this ligand type was evaluated by the brine shrimp test. All the complexes showed a moderate activity.
Ključne reči:
2-Acetylpyridine derivatives / 2-Quinolinecarboxaldehyde derivatives / Biological activity / D-Metal complexesIzvor:
Materials Science Forum, 2007, 555, 423-427Finansiranje / projekti:
- Interakcije prirodnih proizvoda i njihovih analoga sa proteinima i nukleinskim kiselinama (RS-142026)
DOI: 10.4028/www.scientific.net/MSF.555.423
ISSN: 0255-5476
WoS: 000249653700068
Scopus: 2-s2.0-38349028797
Institucija/grupa
IHTMTY - CONF AU - Filipović, N.R. AU - Todorović, Tamara AU - Sladić, Dušan AU - Novaković, Irena AU - Jeremić, D. A. AU - Anđelković, Katarina PY - 2007 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/344 AB - New complexes of Pt(II) with condensation derivatives of ethyl hydrazinoacetate and either 2-acetylpyridine or 2-quinolinecarboxaldehyde, and of Pd(II) with the condensation derivative of ethyl hydrazinoacetate and 2-quinolinecarboxaldehyde were synthesized and characterized by elemental analysis, IR, 1H- and 13C-NMR spectroscopy, and molar conductivity measurements. The complexes have a square planar geometry, ligands binding as bidentates in the neutral form, and the remaining two coordination sites being occupied by chloride ions. Biological activity of new complexes, and of previously synthesized Pd(II), Cd(II), Co(III) and Zn(II) complexes with this ligand type was evaluated by the brine shrimp test. All the complexes showed a moderate activity. C3 - Materials Science Forum T1 - Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands VL - 555 SP - 423 EP - 427 DO - 10.4028/www.scientific.net/MSF.555.423 ER -
@conference{ author = "Filipović, N.R. and Todorović, Tamara and Sladić, Dušan and Novaković, Irena and Jeremić, D. A. and Anđelković, Katarina", year = "2007", abstract = "New complexes of Pt(II) with condensation derivatives of ethyl hydrazinoacetate and either 2-acetylpyridine or 2-quinolinecarboxaldehyde, and of Pd(II) with the condensation derivative of ethyl hydrazinoacetate and 2-quinolinecarboxaldehyde were synthesized and characterized by elemental analysis, IR, 1H- and 13C-NMR spectroscopy, and molar conductivity measurements. The complexes have a square planar geometry, ligands binding as bidentates in the neutral form, and the remaining two coordination sites being occupied by chloride ions. Biological activity of new complexes, and of previously synthesized Pd(II), Cd(II), Co(III) and Zn(II) complexes with this ligand type was evaluated by the brine shrimp test. All the complexes showed a moderate activity.", journal = "Materials Science Forum", title = "Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands", volume = "555", pages = "423-427", doi = "10.4028/www.scientific.net/MSF.555.423" }
Filipović, N.R., Todorović, T., Sladić, D., Novaković, I., Jeremić, D. A.,& Anđelković, K.. (2007). Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands. in Materials Science Forum, 555, 423-427. https://doi.org/10.4028/www.scientific.net/MSF.555.423
Filipović N, Todorović T, Sladić D, Novaković I, Jeremić DA, Anđelković K. Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands. in Materials Science Forum. 2007;555:423-427. doi:10.4028/www.scientific.net/MSF.555.423 .
Filipović, N.R., Todorović, Tamara, Sladić, Dušan, Novaković, Irena, Jeremić, D. A., Anđelković, Katarina, "Synthesis, characterization and biological activity evaluation of novel Pd(II) and Pt(II) complexes with heterocyclic hydrazone ligands" in Materials Science Forum, 555 (2007):423-427, https://doi.org/10.4028/www.scientific.net/MSF.555.423 . .