Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum
Samo za registrovane korisnike
2020
Autori
Vasić, BorislavRalević, Uroš
Cvetanović Zobenica, Katarina
Smiljanić, Milče M.
Gajić, Radoš
Spasenović, Marko
Vollebregt, Sten
Članak u časopisu (Objavljena verzija)
,
Elsevier
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Chemical vapour deposition (CVD) is a promising method for producing large-scale graphene (Gr). Nevertheless, microscopic inhomogeneity of Gr grown on traditional metal substrates such as copper or nickel results in a spatial variation of Gr properties due to long wrinkles formed when the metal substrate shrinks during the cooling part of the production cycle. Recently, molybdenum (Mo) has emerged as an alternative substrate for CVD growth of Gr, mainly due to a better matching of the thermal expansion coefficient of the substrate and Gr. We investigate the quality of multilayer Gr grown on Mo and the relation between Gr morphology and nanoscale mechanical and electrical properties, and spatial homogeneity of these parameters. With atomic force microscopy (AFM) based scratching, Kelvin probe force microscopy, and conductive AFM, we measure friction and wear, surface potential, and local conductivity, respectively. We find that Gr grown on Mo is free of large wrinkles that are common wi...th growth on other metals, although it contains a dense network of small wrinkles. We demonstrate that as a result of this unique and favorable morphology, the Gr studied here has low friction, high wear resistance, and excellent homogeneity of electrical surface potential and conductivity.
Ključne reči:
Graphene / Chemical vapour deposition / Atomic force microscopy / Friction / Wear / Electrical propertiesIzvor:
Applied Surface Science, 2020, 509, 144792-Izdavač:
- Elsevier
Finansiranje / projekti:
- Fizika uređenih nanostruktura i novih materijala u fotonici (RS-MESTD-Basic Research (BR or ON)-171005)
- Mikro, nano-sistemi i senzori za primenu u elektroprivredi, procesnoj industriji i zaštiti životne sredine (RS-MESTD-Technological Development (TD or TR)-32008)
Napomena:
- The peer-reviewed version: http://cer.ihtm.bg.ac.rs/handle/123456789/3351
DOI: 10.1016/j.apsusc.2019.144792
ISSN: 0169-4332
WoS: 000514827600080
Scopus: 2-s2.0-85076245459
Institucija/grupa
IHTMTY - JOUR AU - Vasić, Borislav AU - Ralević, Uroš AU - Cvetanović Zobenica, Katarina AU - Smiljanić, Milče M. AU - Gajić, Radoš AU - Spasenović, Marko AU - Vollebregt, Sten PY - 2020 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3347 AB - Chemical vapour deposition (CVD) is a promising method for producing large-scale graphene (Gr). Nevertheless, microscopic inhomogeneity of Gr grown on traditional metal substrates such as copper or nickel results in a spatial variation of Gr properties due to long wrinkles formed when the metal substrate shrinks during the cooling part of the production cycle. Recently, molybdenum (Mo) has emerged as an alternative substrate for CVD growth of Gr, mainly due to a better matching of the thermal expansion coefficient of the substrate and Gr. We investigate the quality of multilayer Gr grown on Mo and the relation between Gr morphology and nanoscale mechanical and electrical properties, and spatial homogeneity of these parameters. With atomic force microscopy (AFM) based scratching, Kelvin probe force microscopy, and conductive AFM, we measure friction and wear, surface potential, and local conductivity, respectively. We find that Gr grown on Mo is free of large wrinkles that are common with growth on other metals, although it contains a dense network of small wrinkles. We demonstrate that as a result of this unique and favorable morphology, the Gr studied here has low friction, high wear resistance, and excellent homogeneity of electrical surface potential and conductivity. PB - Elsevier T2 - Applied Surface Science T1 - Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum VL - 509 SP - 144792 DO - 10.1016/j.apsusc.2019.144792 ER -
@article{ author = "Vasić, Borislav and Ralević, Uroš and Cvetanović Zobenica, Katarina and Smiljanić, Milče M. and Gajić, Radoš and Spasenović, Marko and Vollebregt, Sten", year = "2020", abstract = "Chemical vapour deposition (CVD) is a promising method for producing large-scale graphene (Gr). Nevertheless, microscopic inhomogeneity of Gr grown on traditional metal substrates such as copper or nickel results in a spatial variation of Gr properties due to long wrinkles formed when the metal substrate shrinks during the cooling part of the production cycle. Recently, molybdenum (Mo) has emerged as an alternative substrate for CVD growth of Gr, mainly due to a better matching of the thermal expansion coefficient of the substrate and Gr. We investigate the quality of multilayer Gr grown on Mo and the relation between Gr morphology and nanoscale mechanical and electrical properties, and spatial homogeneity of these parameters. With atomic force microscopy (AFM) based scratching, Kelvin probe force microscopy, and conductive AFM, we measure friction and wear, surface potential, and local conductivity, respectively. We find that Gr grown on Mo is free of large wrinkles that are common with growth on other metals, although it contains a dense network of small wrinkles. We demonstrate that as a result of this unique and favorable morphology, the Gr studied here has low friction, high wear resistance, and excellent homogeneity of electrical surface potential and conductivity.", publisher = "Elsevier", journal = "Applied Surface Science", title = "Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum", volume = "509", pages = "144792", doi = "10.1016/j.apsusc.2019.144792" }
Vasić, B., Ralević, U., Cvetanović Zobenica, K., Smiljanić, M. M., Gajić, R., Spasenović, M.,& Vollebregt, S.. (2020). Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum. in Applied Surface Science Elsevier., 509, 144792. https://doi.org/10.1016/j.apsusc.2019.144792
Vasić B, Ralević U, Cvetanović Zobenica K, Smiljanić MM, Gajić R, Spasenović M, Vollebregt S. Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum. in Applied Surface Science. 2020;509:144792. doi:10.1016/j.apsusc.2019.144792 .
Vasić, Borislav, Ralević, Uroš, Cvetanović Zobenica, Katarina, Smiljanić, Milče M., Gajić, Radoš, Spasenović, Marko, Vollebregt, Sten, "Low-friction, wear-resistant, and electrically homogeneous multilayer graphene grown by chemical vapor deposition on molybdenum" in Applied Surface Science, 509 (2020):144792, https://doi.org/10.1016/j.apsusc.2019.144792 . .