A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields
Authorized Users Only
2019
Authors
Cvetković, Vesna S.Vukićević, Nataša
Nikolić, Nebojša D.
Baščarević, Zvezdana
Barudžija, Tanja S.
Jovićević, Jovan N.
Article (Published version)
,
Elsevier
Metadata
Show full item recordAbstract
The processes of electrodeposition from magnesium nitrate hexahydrate melt by galvanostatic regime of electrolysis
have been analyzed. The structure of the formed particles was examined by X-ray diffraction (XRD),
which revealed formation of MgO/Mg(OH)2 mixture by molten salt electrolysis. Morphologies of the produced
deposits were characterized by scanning electron microscopy (SEM) technique. The flower-like forms constructed
from very thin needles with sharp tips were predominately formed by electrodeposition at various
current densities and with various amounts of electricity. Aside from that, holes formed from detached hydrogen
bubbles of various shapes and sizes, from dish-like holes to those resulting in honeycomb-like structures were
also observed. Mechanism of formation of the flower-like forms has been elucidated applying the general theory
of disperse deposits formation which is based on the concept of local (spherical and cylindrical) diffusion fields.
It is shown t...hat the growth of the needles occurs under the conditions of predominant spherical diffusion control,
while the contribution of the cylindrical diffusion to the final shapes was negligible. Comparison with
morphologies of deposits obtained by electrodepositions from aqueous magnesium salt electrolytes was also
made and discussed.
Keywords:
Electrolysis / Magnesium oxide/magnesium hydroxide / The flower-like forms / Holes / SEM / XRDSource:
Journal of Electroanalytical Chemistry, 2019, 842, 168-175Publisher:
- Elsevier
Funding / projects:
- Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-MESTD-Basic Research (BR or ON)-172046)
- New approach in designing materials for energy conversion and energy storage systems (RS-MESTD-Basic Research (BR or ON)-172060)
DOI: 10.1016/j.jelechem.2019.04.067
ISSN: 1572-6657
WoS: 000469907700021
Scopus: 2-s2.0-85065177700
Collections
Institution/Community
IHTMTY - JOUR AU - Cvetković, Vesna S. AU - Vukićević, Nataša AU - Nikolić, Nebojša D. AU - Baščarević, Zvezdana AU - Barudžija, Tanja S. AU - Jovićević, Jovan N. PY - 2019 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/3112 AB - The processes of electrodeposition from magnesium nitrate hexahydrate melt by galvanostatic regime of electrolysis have been analyzed. The structure of the formed particles was examined by X-ray diffraction (XRD), which revealed formation of MgO/Mg(OH)2 mixture by molten salt electrolysis. Morphologies of the produced deposits were characterized by scanning electron microscopy (SEM) technique. The flower-like forms constructed from very thin needles with sharp tips were predominately formed by electrodeposition at various current densities and with various amounts of electricity. Aside from that, holes formed from detached hydrogen bubbles of various shapes and sizes, from dish-like holes to those resulting in honeycomb-like structures were also observed. Mechanism of formation of the flower-like forms has been elucidated applying the general theory of disperse deposits formation which is based on the concept of local (spherical and cylindrical) diffusion fields. It is shown that the growth of the needles occurs under the conditions of predominant spherical diffusion control, while the contribution of the cylindrical diffusion to the final shapes was negligible. Comparison with morphologies of deposits obtained by electrodepositions from aqueous magnesium salt electrolytes was also made and discussed. PB - Elsevier T2 - Journal of Electroanalytical Chemistry T1 - A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields VL - 842 SP - 168 EP - 175 DO - 10.1016/j.jelechem.2019.04.067 ER -
@article{ author = "Cvetković, Vesna S. and Vukićević, Nataša and Nikolić, Nebojša D. and Baščarević, Zvezdana and Barudžija, Tanja S. and Jovićević, Jovan N.", year = "2019", abstract = "The processes of electrodeposition from magnesium nitrate hexahydrate melt by galvanostatic regime of electrolysis have been analyzed. The structure of the formed particles was examined by X-ray diffraction (XRD), which revealed formation of MgO/Mg(OH)2 mixture by molten salt electrolysis. Morphologies of the produced deposits were characterized by scanning electron microscopy (SEM) technique. The flower-like forms constructed from very thin needles with sharp tips were predominately formed by electrodeposition at various current densities and with various amounts of electricity. Aside from that, holes formed from detached hydrogen bubbles of various shapes and sizes, from dish-like holes to those resulting in honeycomb-like structures were also observed. Mechanism of formation of the flower-like forms has been elucidated applying the general theory of disperse deposits formation which is based on the concept of local (spherical and cylindrical) diffusion fields. It is shown that the growth of the needles occurs under the conditions of predominant spherical diffusion control, while the contribution of the cylindrical diffusion to the final shapes was negligible. Comparison with morphologies of deposits obtained by electrodepositions from aqueous magnesium salt electrolytes was also made and discussed.", publisher = "Elsevier", journal = "Journal of Electroanalytical Chemistry", title = "A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields", volume = "842", pages = "168-175", doi = "10.1016/j.jelechem.2019.04.067" }
Cvetković, V. S., Vukićević, N., Nikolić, N. D., Baščarević, Z., Barudžija, T. S.,& Jovićević, J. N.. (2019). A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields. in Journal of Electroanalytical Chemistry Elsevier., 842, 168-175. https://doi.org/10.1016/j.jelechem.2019.04.067
Cvetković VS, Vukićević N, Nikolić ND, Baščarević Z, Barudžija TS, Jovićević JN. A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields. in Journal of Electroanalytical Chemistry. 2019;842:168-175. doi:10.1016/j.jelechem.2019.04.067 .
Cvetković, Vesna S., Vukićević, Nataša, Nikolić, Nebojša D., Baščarević, Zvezdana, Barudžija, Tanja S., Jovićević, Jovan N., "A possible mechanism of formation of flower-like MgO/Mg(OH)2 structures by galvanostatic molten salt electrolysis: The concept of local diffusion fields" in Journal of Electroanalytical Chemistry, 842 (2019):168-175, https://doi.org/10.1016/j.jelechem.2019.04.067 . .