The particle size distribution (PSD) as criteria for comparison of silver powders obtained by different methods of synthesis and by conditions of electrolysis
2018
Аутори
Avramović, LjiljanaBugarin, Mile
Milanović, D.
Conić, V.
Pavlović, Miroslav M.
Vuković, Marina
Nikolić, Nebojša D.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Silver powders produced by both electrochemical (galvanostatic (DC) and potentiostatic (POT) regimes of electrolysis) and chemical processes were examined by scanning electron microscope, and particle size distribution (PSD) of the obtained particles was done. In the DC regime, the current densities of -14.4 mA cm-2 for the nitrate (NIT; powder denoted with DC(NIT)) and -13.05 mA cm-2 for the ammonium (AM; DC(AM)) electrolytes were applied. In the POT regime, the used overpotentials were -90 mV (NIT(90)) and -150 mV (NIT(150)) for the nitrate, and -625 mV (AM(625)) and -925 mV (AM(925)) for the ammonium electrolytes. Reduction with hydrazine was used for chemical synthesis (powder denoted with HYD). On the basis of SEM and PSD analysis, Ag powders were grouped into three groups. In the first group DC(AM), AM(925) and HYD powders with the (8.4-8.9 %) volume ratios were placed. In the second group were AM(625) and DC(NIT) powders with the (6.5-6.6 %) volume ratios. NIT(90) and NIT(150) p...owders with the volume ratios of (5.2-5.7 %) made the third group. The obtained volume ratios were correlated with the morphology of synthesized particles in order to perceive advantages and lacks of powder production via electrochemical and chemical routes.
Кључне речи:
Chemical synthesis / Electrolysis / Elektroliza / Hemijska sinteza / Powder / Prah / PSD / PSD / SEM / SEM / Silver / SrebroИзвор:
Journal of Mining and Metallurgy B: Metallurgy, 2018, 54, 3, 291-300Издавач:
- Bor : Technical Faculty
Финансирање / пројекти:
- Електрохемијска синтеза и карактеризација наноструктурираних функционалних материјала за примену у новим технологијама (RS-MESTD-Basic Research (BR or ON)-172046)
DOI: 10.2298/JMMB171002020A
ISSN: 1450-5339
WoS: 000462282900002
Scopus: 2-s2.0-85059594317
Институција/група
IHTMTY - JOUR AU - Avramović, Ljiljana AU - Bugarin, Mile AU - Milanović, D. AU - Conić, V. AU - Pavlović, Miroslav M. AU - Vuković, Marina AU - Nikolić, Nebojša D. PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2395 AB - Silver powders produced by both electrochemical (galvanostatic (DC) and potentiostatic (POT) regimes of electrolysis) and chemical processes were examined by scanning electron microscope, and particle size distribution (PSD) of the obtained particles was done. In the DC regime, the current densities of -14.4 mA cm-2 for the nitrate (NIT; powder denoted with DC(NIT)) and -13.05 mA cm-2 for the ammonium (AM; DC(AM)) electrolytes were applied. In the POT regime, the used overpotentials were -90 mV (NIT(90)) and -150 mV (NIT(150)) for the nitrate, and -625 mV (AM(625)) and -925 mV (AM(925)) for the ammonium electrolytes. Reduction with hydrazine was used for chemical synthesis (powder denoted with HYD). On the basis of SEM and PSD analysis, Ag powders were grouped into three groups. In the first group DC(AM), AM(925) and HYD powders with the (8.4-8.9 %) volume ratios were placed. In the second group were AM(625) and DC(NIT) powders with the (6.5-6.6 %) volume ratios. NIT(90) and NIT(150) powders with the volume ratios of (5.2-5.7 %) made the third group. The obtained volume ratios were correlated with the morphology of synthesized particles in order to perceive advantages and lacks of powder production via electrochemical and chemical routes. PB - Bor : Technical Faculty T2 - Journal of Mining and Metallurgy B: Metallurgy T1 - The particle size distribution (PSD) as criteria for comparison of silver powders obtained by different methods of synthesis and by conditions of electrolysis VL - 54 IS - 3 SP - 291 EP - 300 DO - 10.2298/JMMB171002020A ER -
@article{ author = "Avramović, Ljiljana and Bugarin, Mile and Milanović, D. and Conić, V. and Pavlović, Miroslav M. and Vuković, Marina and Nikolić, Nebojša D.", year = "2018", abstract = "Silver powders produced by both electrochemical (galvanostatic (DC) and potentiostatic (POT) regimes of electrolysis) and chemical processes were examined by scanning electron microscope, and particle size distribution (PSD) of the obtained particles was done. In the DC regime, the current densities of -14.4 mA cm-2 for the nitrate (NIT; powder denoted with DC(NIT)) and -13.05 mA cm-2 for the ammonium (AM; DC(AM)) electrolytes were applied. In the POT regime, the used overpotentials were -90 mV (NIT(90)) and -150 mV (NIT(150)) for the nitrate, and -625 mV (AM(625)) and -925 mV (AM(925)) for the ammonium electrolytes. Reduction with hydrazine was used for chemical synthesis (powder denoted with HYD). On the basis of SEM and PSD analysis, Ag powders were grouped into three groups. In the first group DC(AM), AM(925) and HYD powders with the (8.4-8.9 %) volume ratios were placed. In the second group were AM(625) and DC(NIT) powders with the (6.5-6.6 %) volume ratios. NIT(90) and NIT(150) powders with the volume ratios of (5.2-5.7 %) made the third group. The obtained volume ratios were correlated with the morphology of synthesized particles in order to perceive advantages and lacks of powder production via electrochemical and chemical routes.", publisher = "Bor : Technical Faculty", journal = "Journal of Mining and Metallurgy B: Metallurgy", title = "The particle size distribution (PSD) as criteria for comparison of silver powders obtained by different methods of synthesis and by conditions of electrolysis", volume = "54", number = "3", pages = "291-300", doi = "10.2298/JMMB171002020A" }
Avramović, L., Bugarin, M., Milanović, D., Conić, V., Pavlović, M. M., Vuković, M.,& Nikolić, N. D.. (2018). The particle size distribution (PSD) as criteria for comparison of silver powders obtained by different methods of synthesis and by conditions of electrolysis. in Journal of Mining and Metallurgy B: Metallurgy Bor : Technical Faculty., 54(3), 291-300. https://doi.org/10.2298/JMMB171002020A
Avramović L, Bugarin M, Milanović D, Conić V, Pavlović MM, Vuković M, Nikolić ND. The particle size distribution (PSD) as criteria for comparison of silver powders obtained by different methods of synthesis and by conditions of electrolysis. in Journal of Mining and Metallurgy B: Metallurgy. 2018;54(3):291-300. doi:10.2298/JMMB171002020A .
Avramović, Ljiljana, Bugarin, Mile, Milanović, D., Conić, V., Pavlović, Miroslav M., Vuković, Marina, Nikolić, Nebojša D., "The particle size distribution (PSD) as criteria for comparison of silver powders obtained by different methods of synthesis and by conditions of electrolysis" in Journal of Mining and Metallurgy B: Metallurgy, 54, no. 3 (2018):291-300, https://doi.org/10.2298/JMMB171002020A . .