Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment
Само за регистроване кориснике
2018
Аутори
Krupez, JelenaKovačević, Vesna V.
Jović, Milica
Roglić, Goran
Natić, Maja
Kuraica, Milorad M.
Obradović, Bratislav M.
Dojčinović, Biljana
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined...: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.
Кључне речи:
advanced oxidation processes (AOP) / alkaloid / nicotine / wastewater treatment / water falling film DBDИзвор:
Journal of Physics D-Applied Physics, 2018, 51, 17Издавач:
- Iop Publishing Ltd, Bristol
Финансирање / пројекти:
- Примена унапређених оксидационих процеса и наноструктурисаних оксидних материјала за уклањање загађивача из животне средине, развој и оптимизација инструменталних техника за праћење ефикасности (RS-MESTD-Basic Research (BR or ON)-172030)
- Дијагностика и оптимизација извора плазме значајних за примене (RS-MESTD-Basic Research (BR or ON)-171034)
- Интегрисани системи за уклањање штетних састојака дима и развој технологија за реализацију термоелектрана и енергана без аерозагађења (RS-MESTD-Technological Development (TD or TR)-33022)
DOI: 10.1088/1361-6463/aab632
ISSN: 0022-3727
WoS: 000429231900001
Scopus: 2-s2.0-85045552718
Институција/група
IHTMTY - JOUR AU - Krupez, Jelena AU - Kovačević, Vesna V. AU - Jović, Milica AU - Roglić, Goran AU - Natić, Maja AU - Kuraica, Milorad M. AU - Obradović, Bratislav M. AU - Dojčinović, Biljana PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/2338 AB - Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed. PB - Iop Publishing Ltd, Bristol T2 - Journal of Physics D-Applied Physics T1 - Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment VL - 51 IS - 17 DO - 10.1088/1361-6463/aab632 ER -
@article{ author = "Krupez, Jelena and Kovačević, Vesna V. and Jović, Milica and Roglić, Goran and Natić, Maja and Kuraica, Milorad M. and Obradović, Bratislav M. and Dojčinović, Biljana", year = "2018", abstract = "Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.", publisher = "Iop Publishing Ltd, Bristol", journal = "Journal of Physics D-Applied Physics", title = "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment", volume = "51", number = "17", doi = "10.1088/1361-6463/aab632" }
Krupez, J., Kovačević, V. V., Jović, M., Roglić, G., Natić, M., Kuraica, M. M., Obradović, B. M.,& Dojčinović, B.. (2018). Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics D-Applied Physics Iop Publishing Ltd, Bristol., 51(17). https://doi.org/10.1088/1361-6463/aab632
Krupez J, Kovačević VV, Jović M, Roglić G, Natić M, Kuraica MM, Obradović BM, Dojčinović B. Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics D-Applied Physics. 2018;51(17). doi:10.1088/1361-6463/aab632 .
Krupez, Jelena, Kovačević, Vesna V., Jović, Milica, Roglić, Goran, Natić, Maja, Kuraica, Milorad M., Obradović, Bratislav M., Dojčinović, Biljana, "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment" in Journal of Physics D-Applied Physics, 51, no. 17 (2018), https://doi.org/10.1088/1361-6463/aab632 . .