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On the deactivation mechanism of RuO2–TiO2/Ti anodes prepared by the sol–gel procedure
(Elsevier, 2005)
The deactivation process that leads to the end of titanium supported RuO2-TiO2 coating service life, for anodes prepared from RuO2 and TiO2 sols, as well as by the conventional thermal decomposition of RuCl3 and TiCl3, was ...
Non-toxic poly(vinyl alcohol)/clay composites as electrode material for detection of 4-chlorophenol and 4-nitrophenol
(Elsevier, 2019)
Development of new electrode materials is necessary for the fabrication of sensors with low detection limits, high sensitivity and broad concentration range. Beside analytical parameters, the ability to replace rare and ...
The electrochemical reduction of trinitrotoluene on a platinum wire modified by chemisorbed acetonitrile
(Elsevier, 2010)
The electrochemical reduction of 2,4,6-trinitrotoluene (TNT) was investigated by cyclic voltammetry on a platinum electrode in aqueous sodium chloride solutions with acetonitrile containing different concentrations of TNT. ...
Two-dimensional electrocrystallization of thallium oxide on the single crystal gold surfaces
(Elsevier, 1984)
The electrocrystallization of thin anodic films on metal electrodes continues
provoke interest since the original work of Bewick et al. [1]. These
studies have been focused on the film formation on mercury [1--3] ...
Catalytic effects of monolayers of metals deposited at underpotentials: Oxidation of formic acid on platinum
(Elsevier, 1975)
It was recently shown that the monolayers of some metals deposited at underpotentials
on gold can substantially increase the rates of some redox reactions 1 , and the
rate of oxygen reduction:. This note reports the ...
Oxidation of d-glucose on single-crystal platinum electrodes: A mechanistic study
(Elsevier, 1992)
Reaction kinetics of glucose oxidation on single-crystal platinum electrodes has a pronounced structure sensitivity. Quasi-steady-state measurements show Tafel slopes of 120 mV per decade for Pt(111), but 60 mV per decade ...
Electrochemically deposited iridium-oxide: Estimation of intrinsic activity and stability in oxygen evolution in acid solution
(Elsevier, 2021)
Hydrated iridium oxyhydroxide (IrOx) films were electrochemically deposited from an alkaline oxalic solution at constant anodic potentials and by applying a potential cycling protocol, in both cases with variation of the ...
ALSV investigation of the phase composition of electrolytic Cu + Sn alloys
(Elsevier, 1991)
Anodic linear sweep voltammograms (ALSVs) have been recorded for thin layers of Cu + Sn alloys electrochemically deposited on graphite from a pyrophosphate bath. Three characteristic peaks were found. The first peak, ...
Underpotential deposition of metals in the presence of surfactants: Deposition of thallium and lead on an Ag (100) electrode in the presence of sodium dodecyl sulphate
(Elsevier, 1985)
In this work sodium dodecyl sulphate (SDS) was used to modify the surface of an Ag (100) single crystal electrode. Both the underpotentlal deposition (UPD) and overpotential deposition (OPD) of thallium and lead were studied ...
Anodic stability and electrochromism of electrodeposited ruthenium-iridium coatings on titanium
(Elsevier, 1992)
The anodic behaviour of galvanically plated ruthenium-iridium coatings on titanium was investigated. The dependence of the Tafel slopes and the stability of the coatings for the oxygen evolution reaction in sulphuric acid ...