Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram
Authorized Users Only
2013
Authors
Minić, DuškoPremović, Milena
Ćosović, Vladan
Manasijević, Dragan
Živković, Dragana
Kostov, Ana
Talijan, Nadežda M.
Article (Published version)
Metadata
Show full item recordAbstract
Phase diagram of the Al-Cu-Sb ternary system was investigated experimentally by DTA and SEM-EDS methods and theoretically by CALPHAD method. The liquidus projection, invariant equilibria, three vertical sections: Sb-Al0.5Cu0.5, Al-Cu0.5Sb0.5 and Cu-Al0.5Sb0.5 as well as isothermal sections at 400 degrees C and 200 degrees C were predicted using COST MP0602 thermodynamic database. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Experimentally obtained phase transition temperatures were compared with the results of thermodynamic calculation. Predicted isothermal sections at 400 degrees C and 200 degrees C were compared with the results of the SEM-EDS analysis from this work. In both cases, a good agreement between theoretical calculations and experimental results was obtained.
Keywords:
Al-Cu-Sb system / Phase diagram / Thermal analysis / Thermodynamic predictionSource:
Journal of Alloys and Compounds, 2013, 555, 347-356Publisher:
- Elsevier
Funding / projects:
- Advanced multicomponent metal systems and nanostructured materials with diverse functional properties (RS-MESTD-Basic Research (BR or ON)-172037)
DOI: 10.1016/j.jallcom.2012.12.059
ISSN: 0925-8388
WoS: 000314909700058
Scopus: 2-s2.0-84872522741
Collections
Institution/Community
IHTMTY - JOUR AU - Minić, Duško AU - Premović, Milena AU - Ćosović, Vladan AU - Manasijević, Dragan AU - Živković, Dragana AU - Kostov, Ana AU - Talijan, Nadežda M. PY - 2013 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/1275 AB - Phase diagram of the Al-Cu-Sb ternary system was investigated experimentally by DTA and SEM-EDS methods and theoretically by CALPHAD method. The liquidus projection, invariant equilibria, three vertical sections: Sb-Al0.5Cu0.5, Al-Cu0.5Sb0.5 and Cu-Al0.5Sb0.5 as well as isothermal sections at 400 degrees C and 200 degrees C were predicted using COST MP0602 thermodynamic database. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Experimentally obtained phase transition temperatures were compared with the results of thermodynamic calculation. Predicted isothermal sections at 400 degrees C and 200 degrees C were compared with the results of the SEM-EDS analysis from this work. In both cases, a good agreement between theoretical calculations and experimental results was obtained. PB - Elsevier T2 - Journal of Alloys and Compounds T1 - Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram VL - 555 SP - 347 EP - 356 DO - 10.1016/j.jallcom.2012.12.059 ER -
@article{ author = "Minić, Duško and Premović, Milena and Ćosović, Vladan and Manasijević, Dragan and Živković, Dragana and Kostov, Ana and Talijan, Nadežda M.", year = "2013", abstract = "Phase diagram of the Al-Cu-Sb ternary system was investigated experimentally by DTA and SEM-EDS methods and theoretically by CALPHAD method. The liquidus projection, invariant equilibria, three vertical sections: Sb-Al0.5Cu0.5, Al-Cu0.5Sb0.5 and Cu-Al0.5Sb0.5 as well as isothermal sections at 400 degrees C and 200 degrees C were predicted using COST MP0602 thermodynamic database. In addition, phase transition temperatures of the selected samples with compositions along calculated isopleths were experimentally determined using DTA. Experimentally obtained phase transition temperatures were compared with the results of thermodynamic calculation. Predicted isothermal sections at 400 degrees C and 200 degrees C were compared with the results of the SEM-EDS analysis from this work. In both cases, a good agreement between theoretical calculations and experimental results was obtained.", publisher = "Elsevier", journal = "Journal of Alloys and Compounds", title = "Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram", volume = "555", pages = "347-356", doi = "10.1016/j.jallcom.2012.12.059" }
Minić, D., Premović, M., Ćosović, V., Manasijević, D., Živković, D., Kostov, A.,& Talijan, N. M.. (2013). Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram. in Journal of Alloys and Compounds Elsevier., 555, 347-356. https://doi.org/10.1016/j.jallcom.2012.12.059
Minić D, Premović M, Ćosović V, Manasijević D, Živković D, Kostov A, Talijan NM. Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram. in Journal of Alloys and Compounds. 2013;555:347-356. doi:10.1016/j.jallcom.2012.12.059 .
Minić, Duško, Premović, Milena, Ćosović, Vladan, Manasijević, Dragan, Živković, Dragana, Kostov, Ana, Talijan, Nadežda M., "Experimental investigation and thermodynamic calculations of the Al-Cu-Sb phase diagram" in Journal of Alloys and Compounds, 555 (2013):347-356, https://doi.org/10.1016/j.jallcom.2012.12.059 . .