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Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives
dc.creator | Rašović, Aleksandar | |
dc.creator | Koch, Andreas | |
dc.creator | Kleinpeter, Erich | |
dc.creator | Marković, Rade | |
dc.date.accessioned | 2019-01-30T17:35:12Z | |
dc.date.available | 2019-01-30T17:35:12Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0040-4020 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/1227 | |
dc.description.abstract | Trithiaazapentalene derivatives were prepared by the reaction of 2-alkylidene-4-oxothiazolidines with Lawesson's reagent. They are classified as two structurally different trithiaazapentalene compounds that have different contributions of monocyclic 1,2-dithiole and 1,2,4-dithiazole structures and degrees of aromaticity of the bicyclic trithiaazapentalene system. The electron-donating ability of substituents at the C(5) position of the trithiaazapentalene system is recognized as the main cause for changes in pi-Celectron distribution. This is the first complete study of substituent effects on the structure of trithiapentalenes. | en |
dc.publisher | Oxford : Pergamon-Elsevier Science Ltd | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS// | |
dc.relation | Deutscher Akademischer Austauschdienst (DAAD)-project - 504 252 70 | |
dc.rights | restrictedAccess | |
dc.source | Tetrahedron | |
dc.subject | Trithiapentalene | en |
dc.subject | 1,2-Dithiole | en |
dc.subject | 1,2,4-Dithiazole | en |
dc.subject | 4-Oxothiazolidine | en |
dc.subject | Rearrangement to trithiaazapentalene | en |
dc.subject | Push-pull character | en |
dc.title | Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Коцх, Aндреас; Клеинпетер, Ерицх; Марковиц, Раде; Рашовић, Aлександар; | |
dc.citation.volume | 69 | |
dc.citation.issue | 51 | |
dc.citation.spage | 10849 | |
dc.citation.epage | 10857 | |
dc.citation.other | 69(51): 10849-10857 | |
dc.citation.rank | M21 | |
dc.identifier.doi | 10.1016/j.tet.2013.10.088 | |
dc.identifier.scopus | 2-s2.0-84888646581 | |
dc.identifier.wos | 000328808300009 | |
dc.type.version | publishedVersion |