A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger-Akahira-Sunose's method, and further analysis of these results was performed by Vyazovkin's algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.
Keywords:
Transition metals compounds / Thermochemistry / Density functional theory / Reaction mechanisms
TY - JOUR
AU - Šumar-Ristović, Maja
AU - Gruden-Pavlović, Maja
AU - Zlatar, Matija
AU - Blagojević, Vladimir A.
AU - Anđelković, Katarina
AU - Poleti, Dejan
AU - Minić, Dragica M.
PY - 2012
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/990
AB - A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger-Akahira-Sunose's method, and further analysis of these results was performed by Vyazovkin's algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.
PB - Springer Wien, Wien
T2 - Monatshefte Fur Chemie
T1 - Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands
VL - 143
IS - 8
SP - 1133
EP - 1139
DO - 10.1007/s00706-012-0793-6
ER -
@article{
author = "Šumar-Ristović, Maja and Gruden-Pavlović, Maja and Zlatar, Matija and Blagojević, Vladimir A. and Anđelković, Katarina and Poleti, Dejan and Minić, Dragica M.",
year = "2012",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/990",
abstract = "A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger-Akahira-Sunose's method, and further analysis of these results was performed by Vyazovkin's algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.",
publisher = "Springer Wien, Wien",
journal = "Monatshefte Fur Chemie",
title = "Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands",
volume = "143",
number = "8",
pages = "1133-1139",
doi = "10.1007/s00706-012-0793-6"
}
Šumar-Ristović, M., Gruden-Pavlović, M., Zlatar, M., Blagojević, V. A., Anđelković, K., Poleti, D.,& Minić, D. M. (2012). Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands.
Monatshefte Fur Chemie
Springer Wien, Wien., 143(8), 1133-1139.
https://doi.org/10.1007/s00706-012-0793-6
Šumar-Ristović M, Gruden-Pavlović M, Zlatar M, Blagojević VA, Anđelković K, Poleti D, Minić DM. Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands. Monatshefte Fur Chemie. 2012;143(8):1133-1139
Šumar-Ristović Maja, Gruden-Pavlović Maja, Zlatar Matija, Blagojević Vladimir A., Anđelković Katarina, Poleti Dejan, Minić Dragica M., "Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands" Monatshefte Fur Chemie, 143, no. 8 (2012):1133-1139,
https://doi.org/10.1007/s00706-012-0793-6 .
