Ternary Cu-Sb-Zn system has been thermodynamically assessed by using CALPHAD method and experimentally by DSC and SEM-EDS methods. The liquidus projection, invariant equilibria, several vertical sections and isothermal sections at 450 degrees C and 25 degrees C were predicted using COST 531 Thermodynamic Database. Phase transition temperatures of alloys along three predicted vertical sections of the Cu-Sb-Zn ternary system with molar ratios Cu:Zn = 1: 3, Cu: Zn = 1 and Sb:Zn = 1, were determined by DSC analysis. Predicted isothermal sections at 450 degrees C and 25 degrees C were compared with the results of the SEM-EDS analysis. The calculated values were found to be in a good agreement with the experimentally obtained values and literature data.
TY - JOUR
AU - Minić, Duško
AU - Manasijević, Dragan
AU - Ćosović, Vladan
AU - Talijan, Nadežda M.
AU - Zivkovic, Zivan
AU - Živković, Dragana
AU - Premović, Milena
PY - 2012
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/988
AB - Ternary Cu-Sb-Zn system has been thermodynamically assessed by using CALPHAD method and experimentally by DSC and SEM-EDS methods. The liquidus projection, invariant equilibria, several vertical sections and isothermal sections at 450 degrees C and 25 degrees C were predicted using COST 531 Thermodynamic Database. Phase transition temperatures of alloys along three predicted vertical sections of the Cu-Sb-Zn ternary system with molar ratios Cu:Zn = 1: 3, Cu: Zn = 1 and Sb:Zn = 1, were determined by DSC analysis. Predicted isothermal sections at 450 degrees C and 25 degrees C were compared with the results of the SEM-EDS analysis. The calculated values were found to be in a good agreement with the experimentally obtained values and literature data.
PB - Elsevier
T2 - Journal of Alloys and Compounds
T1 - Experimental investigation and thermodynamic prediction of the Cu-Sb-Zn phase diagram
VL - 517
SP - 31
EP - 39
DO - 10.1016/j.jallcom.2011.11.130
ER -
@article{
author = "Minić, Duško and Manasijević, Dragan and Ćosović, Vladan and Talijan, Nadežda M. and Zivkovic, Zivan and Živković, Dragana and Premović, Milena",
year = "2012",
abstract = "Ternary Cu-Sb-Zn system has been thermodynamically assessed by using CALPHAD method and experimentally by DSC and SEM-EDS methods. The liquidus projection, invariant equilibria, several vertical sections and isothermal sections at 450 degrees C and 25 degrees C were predicted using COST 531 Thermodynamic Database. Phase transition temperatures of alloys along three predicted vertical sections of the Cu-Sb-Zn ternary system with molar ratios Cu:Zn = 1: 3, Cu: Zn = 1 and Sb:Zn = 1, were determined by DSC analysis. Predicted isothermal sections at 450 degrees C and 25 degrees C were compared with the results of the SEM-EDS analysis. The calculated values were found to be in a good agreement with the experimentally obtained values and literature data.",
publisher = "Elsevier",
journal = "Journal of Alloys and Compounds",
title = "Experimental investigation and thermodynamic prediction of the Cu-Sb-Zn phase diagram",
volume = "517",
pages = "31-39",
doi = "10.1016/j.jallcom.2011.11.130"
}
Minić, D., Manasijević, D., Ćosović, V., Talijan, N. M., Zivkovic, Z., Živković, D.,& Premović, M.. (2012). Experimental investigation and thermodynamic prediction of the Cu-Sb-Zn phase diagram. in Journal of Alloys and Compounds
Elsevier., 517, 31-39.
https://doi.org/10.1016/j.jallcom.2011.11.130
Minić D, Manasijević D, Ćosović V, Talijan NM, Zivkovic Z, Živković D, Premović M. Experimental investigation and thermodynamic prediction of the Cu-Sb-Zn phase diagram. in Journal of Alloys and Compounds. 2012;517:31-39.
doi:10.1016/j.jallcom.2011.11.130 .
Minić, Duško, Manasijević, Dragan, Ćosović, Vladan, Talijan, Nadežda M., Zivkovic, Zivan, Živković, Dragana, Premović, Milena, "Experimental investigation and thermodynamic prediction of the Cu-Sb-Zn phase diagram" in Journal of Alloys and Compounds, 517 (2012):31-39,
https://doi.org/10.1016/j.jallcom.2011.11.130 . .
