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dc.creatorPetković, Branka B.
dc.creatorStevanović, Sanja
dc.creatorBudimir, Milana V.
dc.creatorSovilj, Sofija P.
dc.creatorJovanović, Vladislava M.
dc.date.accessioned2019-01-30T17:29:45Z
dc.date.available2019-01-30T17:29:45Z
dc.date.issued2012
dc.identifier.issn1040-0397
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/973
dc.description.abstractMixed ligand dinuclear copper(II) complexes of the general formula [Cu2(Rdtc)tpmc)](ClO4)3 with octaazamacrocyclic ligand tpmc and four different heterocyclic dithiocarbamate ligands Rdtc-, as well as the complexes [Cu2(tpmc)](ClO4)4 and [Cu(tpmc)](ClO4)2 center dot 2H2O were studied in aqueous NaClO4 and HClO4 solutions by cyclic voltammetry on glassy carbon electrode. The electrochemical properties of the ligands and Cu(II) complexes were correlated with their electronic structure. Conductometric experiments showed different stoichiometry in complexation of tpmc with Cu2+ ions and transport of ions in acetonitrile and in aqueous media. These studies clarified the application of this macrocyclic ligand as ionophore in a PVC membrane copper(II) selective electrode and contributed elucidation of its sensor properties.en
dc.publisherWiley-Blackwell, Malden
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.rightsrestrictedAccess
dc.sourceElectroanalysis
dc.subjectCopper(II) complexesen
dc.subjectCyclic voltammetryen
dc.subjecttpmc ligandsen
dc.subjectConductometryen
dc.subjectCu(II) sensorsen
dc.titleElectrochemical Examination of Copper(II) Complexes with Octaazamacrocyclic Ligand and Heterocyclic Dithiocarbamateen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЈовановић, Владислава; Будимир, М.; Стевановић, Сања; Совиљ, С. П.; Петковиц, Б.;
dc.citation.volume24
dc.citation.issue7
dc.citation.spage1605
dc.citation.epage1612
dc.citation.other24(7): 1605-1612
dc.citation.rankM21
dc.identifier.doi10.1002/elan.201200120
dc.identifier.rcubConv_2820
dc.identifier.scopus2-s2.0-84863548644
dc.identifier.wos000305999200016
dc.type.versionpublishedVersion


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