Macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) was synthesized by suspension copolymerization and functionalized with diethylene triamine (PGME-deta). The effect of pH, contact time, and sorbent mass on sorption efficiency of initial and functionalized copolymer sample for removal of Acid Orange 10 dye from aqueous solutions was studied. No dye was sorbed by nonfunctionalized copolymer, indicating that sorption of Acid Orange 10 by PGME-deta is specific, through amino groups. The isotherm data are best fitted by Langmuir model, indicating homogeneous distribution of active sites in PGME-deta as well as monolayer sorption. Sorption kinetics study showed that the sorption of Acid Orange 10 by PGME-deta obeys the pseudo-second-order kinetic model. It was shown that PGME-deta selectively sorbs Acid Orange 10 from binary solution with Bezaktiv Rot reactive dye. The comparison of sorption characteristics of PGME-deta with activated carbon showed that this fu...nctionalized copolymer might be used as an alternative sorbent for textile dyes.
TY - JOUR
AU - Sandić, Zvjezdana P.
AU - Nastasović, Aleksandra
AU - Jović-Jovičić, Nataša
AU - Milutinović Nikolić, Aleksandra
AU - Jovanović, Dušan M.
PY - 2011
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/911
AB - Macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) was synthesized by suspension copolymerization and functionalized with diethylene triamine (PGME-deta). The effect of pH, contact time, and sorbent mass on sorption efficiency of initial and functionalized copolymer sample for removal of Acid Orange 10 dye from aqueous solutions was studied. No dye was sorbed by nonfunctionalized copolymer, indicating that sorption of Acid Orange 10 by PGME-deta is specific, through amino groups. The isotherm data are best fitted by Langmuir model, indicating homogeneous distribution of active sites in PGME-deta as well as monolayer sorption. Sorption kinetics study showed that the sorption of Acid Orange 10 by PGME-deta obeys the pseudo-second-order kinetic model. It was shown that PGME-deta selectively sorbs Acid Orange 10 from binary solution with Bezaktiv Rot reactive dye. The comparison of sorption characteristics of PGME-deta with activated carbon showed that this functionalized copolymer might be used as an alternative sorbent for textile dyes.
PB - Wiley-Blackwell, Malden
T2 - Journal of Applied Polymer Science
T1 - Sorption of Textile Dye from Aqueous Solution by Macroporous Amino-Functionalized Copolymer
VL - 121
IS - 1
SP - 234
EP - 242
DO - 10.1002/app.33537
ER -
@article{
author = "Sandić, Zvjezdana P. and Nastasović, Aleksandra and Jović-Jovičić, Nataša and Milutinović Nikolić, Aleksandra and Jovanović, Dušan M.",
year = "2011",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/911",
abstract = "Macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) was synthesized by suspension copolymerization and functionalized with diethylene triamine (PGME-deta). The effect of pH, contact time, and sorbent mass on sorption efficiency of initial and functionalized copolymer sample for removal of Acid Orange 10 dye from aqueous solutions was studied. No dye was sorbed by nonfunctionalized copolymer, indicating that sorption of Acid Orange 10 by PGME-deta is specific, through amino groups. The isotherm data are best fitted by Langmuir model, indicating homogeneous distribution of active sites in PGME-deta as well as monolayer sorption. Sorption kinetics study showed that the sorption of Acid Orange 10 by PGME-deta obeys the pseudo-second-order kinetic model. It was shown that PGME-deta selectively sorbs Acid Orange 10 from binary solution with Bezaktiv Rot reactive dye. The comparison of sorption characteristics of PGME-deta with activated carbon showed that this functionalized copolymer might be used as an alternative sorbent for textile dyes.",
publisher = "Wiley-Blackwell, Malden",
journal = "Journal of Applied Polymer Science",
title = "Sorption of Textile Dye from Aqueous Solution by Macroporous Amino-Functionalized Copolymer",
volume = "121",
number = "1",
pages = "234-242",
doi = "10.1002/app.33537"
}
Sandić, Z. P., Nastasović, A., Jović-Jovičić, N., Milutinović Nikolić, A.,& Jovanović, D. M. (2011). Sorption of Textile Dye from Aqueous Solution by Macroporous Amino-Functionalized Copolymer.
Journal of Applied Polymer Science
Wiley-Blackwell, Malden., 121(1), 234-242.
https://doi.org/10.1002/app.33537
Sandić ZP, Nastasović A, Jović-Jovičić N, Milutinović Nikolić A, Jovanović DM. Sorption of Textile Dye from Aqueous Solution by Macroporous Amino-Functionalized Copolymer. Journal of Applied Polymer Science. 2011;121(1):234-242
Sandić Zvjezdana P., Nastasović Aleksandra, Jović-Jovičić Nataša, Milutinović Nikolić Aleksandra, Jovanović Dušan M., "Sorption of Textile Dye from Aqueous Solution by Macroporous Amino-Functionalized Copolymer" Journal of Applied Polymer Science, 121, no. 1 (2011):234-242,
https://doi.org/10.1002/app.33537 .
