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dc.creatorŠegan, Dejan
dc.creatorVukicevic, Rastko D.
dc.creatorŠegan, Sandra
dc.creatorŠojić, Nešo
dc.creatorBuriez, Olivier
dc.creatorManojlović, Dragan
dc.date.accessioned2019-01-30T17:27:23Z
dc.date.available2019-01-30T17:27:23Z
dc.date.issued2011
dc.identifier.issn0013-4686
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/861
dc.description.abstractCyclic voltammetry and ultramicroelectrodes were used to investigate the kinetic aspects of the electrochemical bromination of 3,4,6-tri-O-acetyl-D-glucal (1) in acetonitrile (AN), dichloromethane (DCM), and dimethylsulfoxide (DMSO). Qualitative and quantitative results, determined notably from the kinetic parameter [glucal]/nu representing the competition between glucal concentration and time, clearly showed that glucal bromination depended on the nature of both the solvent and the in situ electrogenerated reactive brominated species (Br-2 or Br-3(-)) obtained from the oxidation of a bromide salt. It was especially shown that Br-2 reacted more rapidly than Br-3(-) towards (1). On the other hand, the reactivity of both brominated species appeared to follow the solvent polarity order since the highest reactivity was obtained in DMSO whereas the lowest one was found in DCM.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationMinistry of Science of the Republic of Serbia
dc.rightsrestrictedAccess
dc.sourceElectrochimica Acta
dc.subjectKineticen
dc.subjectBrominationen
dc.subjectGlycalen
dc.subjectCyclic voltammetryen
dc.titleKinetic investigations of the electrochemical bromination of peracetylated D-glucal in organic solventsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractБуриез, Оливиер; Вукицевиц, Растко Д.; Сојиц, Несо; Сеган, Дејан; Шеган, Сандра; Манојловиц, Драган;
dc.citation.volume56
dc.citation.issue27
dc.citation.spage9968
dc.citation.epage9972
dc.citation.other56(27): 9968-9972
dc.citation.rankM21
dc.identifier.doi10.1016/j.electacta.2011.08.085
dc.identifier.rcubConv_2695
dc.identifier.scopus2-s2.0-80054931632
dc.identifier.wos000297399100040
dc.type.versionpublishedVersion


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