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dc.creatorVidakovic-Koch, Tanja R.
dc.creatorPanić, Vladimir
dc.creatorAndric, Milan
dc.creatorPetkovska, Menka
dc.creatorSundmacher, Kai
dc.date.accessioned2019-01-30T17:27:09Z
dc.date.available2019-01-30T17:27:09Z
dc.date.issued2011
dc.identifier.issn1932-7447
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/852
dc.description.abstractIn this work, a nonlinear frequency response (NLFR) analysis was used for a first time in a theoretical study of nonlinear behavior of electrochemical (EC) ferrocyanide oxidation as a simple model reaction. Analytical expressions of the first- and second-order frequency response functions (FRFs) are derived. The first-order FRF is equivalent to the EC admittance and contains information about the linear behavior of the system, whereas the second-order FRF contains additional nonlinear information. The influence of different parameters, such as the heterogeneous rate constant, solution resistance, double-layer capacitance, diffusion coefficients of the reacting species, and electrode rotation rate on the characteristics of the first- and second-order FRFs was checked and discussed. It was found that the second-order FRF is more sensitive to the changes of the studied parameters than the first-order FRF. Experimental verification of the NLFR analysis of EC ferrocyanide oxidation is presented in Part II of this worken
dc.publisherAmer Chemical Soc, Washington
dc.relationMax Planck Society, Germany
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172022/RS//
dc.rightsrestrictedAccess
dc.sourceJournal of Physical Chemistry C
dc.titleNonlinear Frequency Response Analysis of the Ferrocyanide Oxidation Kinetics. Part I. A Theoretical Analysisen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractПанић, Владимир; Видаковиц-Коцх, Тања Р.; Петковска, Менка; Сундмацхер, Каи; Aндриц, Милан;
dc.citation.volume115
dc.citation.issue35
dc.citation.spage17341
dc.citation.epage17351
dc.citation.other115(35): 17341-17351
dc.citation.rankaM21
dc.identifier.doi10.1021/jp201297v
dc.identifier.rcubConv_2653
dc.identifier.scopus2-s2.0-80052331979
dc.identifier.wos000294386000016
dc.type.versionpublishedVersion


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