The non-periodic, periodic and chaotic regimes in the Bray-Liebhafsky (BL) oscillatory reaction observed in a continuously fed well stirred tank reactor (CSTR) under isothermal conditions at various inflow concentrations of the sulfuric acid were experimentally studied. In each series (at any fixed temperature), termination of oscillatory behavior via saddle loop infinite period bifurcation (SNIPER) as well as some kind of the Andronov-Hopf bifurcation is presented. In addition, it was found that an increase of temperature, in different series of experiments resulted in the shift of bifurcation point towards higher values of sulfuric acid concentration.
Keywords:
Bray-Liebhafsky / oscillatory reaction / control by sulfuric acid and temperature / Andronov-Hopf bifurcation
Source:
Russian Journal of Physical Chemistry A, 2011, 85, 13, 2310-2316
TY - JOUR
AU - Pejić, Nataša
AU - Vujković, Milica
AU - Maksimović, Jelena
AU - Ivanović-Šašić, Ana
AU - Anić, Slobodan
AU - Čupić, Željko
AU - Kolar-Anić, Ljiljana
PY - 2011
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/837
AB - The non-periodic, periodic and chaotic regimes in the Bray-Liebhafsky (BL) oscillatory reaction observed in a continuously fed well stirred tank reactor (CSTR) under isothermal conditions at various inflow concentrations of the sulfuric acid were experimentally studied. In each series (at any fixed temperature), termination of oscillatory behavior via saddle loop infinite period bifurcation (SNIPER) as well as some kind of the Andronov-Hopf bifurcation is presented. In addition, it was found that an increase of temperature, in different series of experiments resulted in the shift of bifurcation point towards higher values of sulfuric acid concentration.
PB - Maik Nauka/Interperiodica/Springer, New York
T2 - Russian Journal of Physical Chemistry A
T1 - Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature
VL - 85
IS - 13
SP - 2310
EP - 2316
DO - 10.1134/S0036024411130231
ER -
@article{
author = "Pejić, Nataša and Vujković, Milica and Maksimović, Jelena and Ivanović-Šašić, Ana and Anić, Slobodan and Čupić, Željko and Kolar-Anić, Ljiljana",
year = "2011",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/837",
abstract = "The non-periodic, periodic and chaotic regimes in the Bray-Liebhafsky (BL) oscillatory reaction observed in a continuously fed well stirred tank reactor (CSTR) under isothermal conditions at various inflow concentrations of the sulfuric acid were experimentally studied. In each series (at any fixed temperature), termination of oscillatory behavior via saddle loop infinite period bifurcation (SNIPER) as well as some kind of the Andronov-Hopf bifurcation is presented. In addition, it was found that an increase of temperature, in different series of experiments resulted in the shift of bifurcation point towards higher values of sulfuric acid concentration.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature",
volume = "85",
number = "13",
pages = "2310-2316",
doi = "10.1134/S0036024411130231"
}
Pejić, N., Vujković, M., Maksimović, J., Ivanović-Šašić, A., Anić, S., Čupić, Ž.,& Kolar-Anić, L. (2011). Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature.
Russian Journal of Physical Chemistry A
Maik Nauka/Interperiodica/Springer, New York., 85(13), 2310-2316.
https://doi.org/10.1134/S0036024411130231
Pejić N, Vujković M, Maksimović J, Ivanović-Šašić A, Anić S, Čupić Ž, Kolar-Anić L. Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature. Russian Journal of Physical Chemistry A. 2011;85(13):2310-2316
Pejić Nataša, Vujković Milica, Maksimović Jelena, Ivanović-Šašić Ana, Anić Slobodan, Čupić Željko, Kolar-Anić Ljiljana, "Dynamic behavior of the bray-liebhafsky oscillatory reaction controlled by sulfuric acid and temperature" Russian Journal of Physical Chemistry A, 85, no. 13 (2011):2310-2316,
https://doi.org/10.1134/S0036024411130231 .
