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Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]

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2002
0354-75310212529S.pdf (271.6Kb)
Authors
Skala, Dejan
Orlović, Aleksandar
Marković, Bojana
Terlecki-Baričević, Ana V.
Jovanović, D.
Article (Published version)
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Abstract
The performed investigations were directed toward the analysis of the performance and activity of the fresh and regenerated Cyanamid HDS 20C catalyst in a laboratory batch reactor (2 dm3) for the HDS of the diesel fraction (light gas oil, LGO). Testing of the regenerated catalyst was performed with light gas oil (LGO) of different characteristics. The determined values of the reaction rate constant were compared to some published data in the literature for the HDS of specific sulfur compounds as well as the values of the activation energy. The rates of deactivation of the fresh and regenerated catalyst actually existed compared to some other results recently published in the literature. However, such an observed differences were not sufficient to derive a relation which could be used for the determination of the rate of catalyst deactivation.
Keywords:
Catalyst activity / Diesel fraction / HDS / Kinetics / LGO
Source:
Chemical Industry and Chemical Engineering Quarterly / CICEQ, 2002, 8, 4, 529-532
Publisher:
  • Association of the Chemical Engineers of Serbia

ISSN: 1451-9372

Scopus: 2-s2.0-85034587868
[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_cer_83
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/83
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Skala, Dejan
AU  - Orlović, Aleksandar
AU  - Marković, Bojana
AU  - Terlecki-Baričević, Ana V.
AU  - Jovanović, D.
PY  - 2002
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/83
AB  - The performed investigations were directed toward the analysis of the performance and activity of the fresh and regenerated Cyanamid HDS 20C catalyst in a laboratory batch reactor (2 dm3) for the HDS of the diesel fraction (light gas oil, LGO). Testing of the regenerated catalyst was performed with light gas oil (LGO) of different characteristics. The determined values of the reaction rate constant were compared to some published data in the literature for the HDS of specific sulfur compounds as well as the values of the activation energy. The rates of deactivation of the fresh and regenerated catalyst actually existed compared to some other results recently published in the literature. However, such an observed differences were not sufficient to derive a relation which could be used for the determination of the rate of catalyst deactivation.
PB  - Association of the Chemical Engineers of Serbia
T2  - Chemical Industry and Chemical Engineering Quarterly / CICEQ
T1  - Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]
VL  - 8
IS  - 4
SP  - 529
EP  - 532
UR  - https://hdl.handle.net/21.15107/rcub_cer_83
ER  - 
@article{
author = "Skala, Dejan and Orlović, Aleksandar and Marković, Bojana and Terlecki-Baričević, Ana V. and Jovanović, D.",
year = "2002",
abstract = "The performed investigations were directed toward the analysis of the performance and activity of the fresh and regenerated Cyanamid HDS 20C catalyst in a laboratory batch reactor (2 dm3) for the HDS of the diesel fraction (light gas oil, LGO). Testing of the regenerated catalyst was performed with light gas oil (LGO) of different characteristics. The determined values of the reaction rate constant were compared to some published data in the literature for the HDS of specific sulfur compounds as well as the values of the activation energy. The rates of deactivation of the fresh and regenerated catalyst actually existed compared to some other results recently published in the literature. However, such an observed differences were not sufficient to derive a relation which could be used for the determination of the rate of catalyst deactivation.",
publisher = "Association of the Chemical Engineers of Serbia",
journal = "Chemical Industry and Chemical Engineering Quarterly / CICEQ",
title = "Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]",
volume = "8",
number = "4",
pages = "529-532",
url = "https://hdl.handle.net/21.15107/rcub_cer_83"
}
Skala, D., Orlović, A., Marković, B., Terlecki-Baričević, A. V.,& Jovanović, D.. (2002). Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]. in Chemical Industry and Chemical Engineering Quarterly / CICEQ
Association of the Chemical Engineers of Serbia., 8(4), 529-532.
https://hdl.handle.net/21.15107/rcub_cer_83
Skala D, Orlović A, Marković B, Terlecki-Baričević AV, Jovanović D. Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]. in Chemical Industry and Chemical Engineering Quarterly / CICEQ. 2002;8(4):529-532.
https://hdl.handle.net/21.15107/rcub_cer_83 .
Skala, Dejan, Orlović, Aleksandar, Marković, Bojana, Terlecki-Baričević, Ana V., Jovanović, D., "Hydrodesulfurization of light gas oil - kinetic determination in a batch reactor [Hidrodesulfurizacija lakog gasnog ulja - ispitivanje kinetike HDS u šaržnom reaktoru]" in Chemical Industry and Chemical Engineering Quarterly / CICEQ, 8, no. 4 (2002):529-532,
https://hdl.handle.net/21.15107/rcub_cer_83 .

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