On the specific surface area of nanoporous materials
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2011
Authors
Detsi, E.De, Jong E.
Zinchenko, A.
Vuković, Zorica

Vukovic, I.
Punzhin, S.
Loos, K.

ten, Brinke G.
De, Raedt H. A.
Onck, P. R.
De, Hosson J. T. M.
Article (Published version)

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A proper quantification of the specific surface area of nanoporous materials is necessary for a better understanding of the properties that are affected by the high surface-area-to-volume ratio of nanoporous metals, nanoporous polymers and nanoporous ceramics. In this paper we derive an analytical expression that relates the specific surface area of arbitrary nanoporous materials to their solid bulk density and ligament size. Computed specific surface areas of porous materials with regular nanopores are in good agreement with the expression derived. These regular void geometries include single and double gyroid structures, as well as materials with spherical and cylindrical nanopores. Validation of the expression for disordered nanoporous materials is performed by investigation of the specific surface areas of various nanoporous gold electrodes in the double-layer charging regime.
Keywords:
Specific surface area / Nanoporous materials / Catalysts / Sensors / ActuatorsSource:
Acta Materialia, 2011, 59, 20, 7488-7497Publisher:
- Oxford : Pergamon-Elsevier Science Ltd
Funding / projects:
- Netherlands Organization for Scientific Research (NWO-The Hague) - 017.005.026
- Zernike Institute for Advanced Materials
DOI: 10.1016/j.actamat.2011.08.025
ISSN: 1359-6454
WoS: 000297822200006
Scopus: 2-s2.0-80053965794
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IHTMTY - JOUR AU - Detsi, E. AU - De, Jong E. AU - Zinchenko, A. AU - Vuković, Zorica AU - Vukovic, I. AU - Punzhin, S. AU - Loos, K. AU - ten, Brinke G. AU - De, Raedt H. A. AU - Onck, P. R. AU - De, Hosson J. T. M. PY - 2011 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/815 AB - A proper quantification of the specific surface area of nanoporous materials is necessary for a better understanding of the properties that are affected by the high surface-area-to-volume ratio of nanoporous metals, nanoporous polymers and nanoporous ceramics. In this paper we derive an analytical expression that relates the specific surface area of arbitrary nanoporous materials to their solid bulk density and ligament size. Computed specific surface areas of porous materials with regular nanopores are in good agreement with the expression derived. These regular void geometries include single and double gyroid structures, as well as materials with spherical and cylindrical nanopores. Validation of the expression for disordered nanoporous materials is performed by investigation of the specific surface areas of various nanoporous gold electrodes in the double-layer charging regime. PB - Oxford : Pergamon-Elsevier Science Ltd T2 - Acta Materialia T1 - On the specific surface area of nanoporous materials VL - 59 IS - 20 SP - 7488 EP - 7497 DO - 10.1016/j.actamat.2011.08.025 ER -
@article{ author = "Detsi, E. and De, Jong E. and Zinchenko, A. and Vuković, Zorica and Vukovic, I. and Punzhin, S. and Loos, K. and ten, Brinke G. and De, Raedt H. A. and Onck, P. R. and De, Hosson J. T. M.", year = "2011", abstract = "A proper quantification of the specific surface area of nanoporous materials is necessary for a better understanding of the properties that are affected by the high surface-area-to-volume ratio of nanoporous metals, nanoporous polymers and nanoporous ceramics. In this paper we derive an analytical expression that relates the specific surface area of arbitrary nanoporous materials to their solid bulk density and ligament size. Computed specific surface areas of porous materials with regular nanopores are in good agreement with the expression derived. These regular void geometries include single and double gyroid structures, as well as materials with spherical and cylindrical nanopores. Validation of the expression for disordered nanoporous materials is performed by investigation of the specific surface areas of various nanoporous gold electrodes in the double-layer charging regime.", publisher = "Oxford : Pergamon-Elsevier Science Ltd", journal = "Acta Materialia", title = "On the specific surface area of nanoporous materials", volume = "59", number = "20", pages = "7488-7497", doi = "10.1016/j.actamat.2011.08.025" }
Detsi, E., De, J. E., Zinchenko, A., Vuković, Z., Vukovic, I., Punzhin, S., Loos, K., ten, B. G., De, R. H. A., Onck, P. R.,& De, H. J. T. M.. (2011). On the specific surface area of nanoporous materials. in Acta Materialia Oxford : Pergamon-Elsevier Science Ltd., 59(20), 7488-7497. https://doi.org/10.1016/j.actamat.2011.08.025
Detsi E, De JE, Zinchenko A, Vuković Z, Vukovic I, Punzhin S, Loos K, ten BG, De RHA, Onck PR, De HJTM. On the specific surface area of nanoporous materials. in Acta Materialia. 2011;59(20):7488-7497. doi:10.1016/j.actamat.2011.08.025 .
Detsi, E., De, Jong E., Zinchenko, A., Vuković, Zorica, Vukovic, I., Punzhin, S., Loos, K., ten, Brinke G., De, Raedt H. A., Onck, P. R., De, Hosson J. T. M., "On the specific surface area of nanoporous materials" in Acta Materialia, 59, no. 20 (2011):7488-7497, https://doi.org/10.1016/j.actamat.2011.08.025 . .