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Surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process: N-2 sorption and XPS studies

Samo za registrovane korisnike
2011
Autori
Nikolova, Dimitrinka
Krstić, Jugoslav
Spasov, L.
Simeonov, D.
Lončarević, Davor
Stefanov, Pl.
Jovanović, Dušan M.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentu
Apstrakt
The effect of the type of the silica gel pore structure on the surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process has been examined applying N-2 sorption and X-ray photoelectron spectroscopy techniques. The nickel catalyst precursors with identical composition (SiO2/Ni = 1.0) has been synthesized by precipitation of Ni(NO3)(2) center dot 6H(2)O solution with Na2CO3 solution on the three types of silica gel with different pore structures. It is shown that the usage of the silica gel supports with different texture as source of SiO2 causes different location of Ni-species into the support pores and on the external surface area. The XPS data confirm the formation of surface species with different strength of interaction and different dispersion. These surface characteristics of the precursors will predetermine the formation of the active nickel metallic phase as well as the mass transfer of the reactants and products to and from the cat...alytic sites.

Ključne reči:
surface properties / Ni-silica gel catalyst / hydrogenation / X-ray photoelectron spectroscopy / N-2 sorption
Izvor:
Russian Journal of Physical Chemistry A, 2011, 85, 13, 2380-2385
Izdavač:
  • Maik Nauka/Interperiodica/Springer, New York
Projekti:
  • Mezoporozni i nanomaterijali u katalitičkim i sorpcionim procesima (RS-166001)

DOI: 10.1134/S0036024411130188

ISSN: 0036-0244

WoS: 000297922700025

Scopus: 2-s2.0-84937015715
[ Google Scholar ]
4
4
URI
http://cer.ihtm.bg.ac.rs/handle/123456789/811
Kolekcije
  • Radovi istraživača / Researchers' publications
Institucija
IHTM
TY  - JOUR
AU  - Nikolova, Dimitrinka
AU  - Krstić, Jugoslav
AU  - Spasov, L.
AU  - Simeonov, D.
AU  - Lončarević, Davor
AU  - Stefanov, Pl.
AU  - Jovanović, Dušan M.
PY  - 2011
UR  - http://cer.ihtm.bg.ac.rs/handle/123456789/811
AB  - The effect of the type of the silica gel pore structure on the surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process has been examined applying N-2 sorption and X-ray photoelectron spectroscopy techniques. The nickel catalyst precursors with identical composition (SiO2/Ni = 1.0) has been synthesized by precipitation of Ni(NO3)(2) center dot 6H(2)O solution with Na2CO3 solution on the three types of silica gel with different pore structures. It is shown that the usage of the silica gel supports with different texture as source of SiO2 causes different location of Ni-species into the support pores and on the external surface area. The XPS data confirm the formation of surface species with different strength of interaction and different dispersion. These surface characteristics of the precursors will predetermine the formation of the active nickel metallic phase as well as the mass transfer of the reactants and products to and from the catalytic sites.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Russian Journal of Physical Chemistry A
T1  - Surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process: N-2 sorption and XPS studies
VL  - 85
IS  - 13
SP  - 2380
EP  - 2385
DO  - 10.1134/S0036024411130188
ER  - 
@article{
author = "Nikolova, Dimitrinka and Krstić, Jugoslav and Spasov, L. and Simeonov, D. and Lončarević, Davor and Stefanov, Pl. and Jovanović, Dušan M.",
year = "2011",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/811",
abstract = "The effect of the type of the silica gel pore structure on the surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process has been examined applying N-2 sorption and X-ray photoelectron spectroscopy techniques. The nickel catalyst precursors with identical composition (SiO2/Ni = 1.0) has been synthesized by precipitation of Ni(NO3)(2) center dot 6H(2)O solution with Na2CO3 solution on the three types of silica gel with different pore structures. It is shown that the usage of the silica gel supports with different texture as source of SiO2 causes different location of Ni-species into the support pores and on the external surface area. The XPS data confirm the formation of surface species with different strength of interaction and different dispersion. These surface characteristics of the precursors will predetermine the formation of the active nickel metallic phase as well as the mass transfer of the reactants and products to and from the catalytic sites.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Russian Journal of Physical Chemistry A",
title = "Surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process: N-2 sorption and XPS studies",
volume = "85",
number = "13",
pages = "2380-2385",
doi = "10.1134/S0036024411130188"
}
Nikolova D, Krstić J, Spasov L, Simeonov D, Lončarević D, Stefanov P, Jovanović DM. Surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process: N-2 sorption and XPS studies. Russian Journal of Physical Chemistry A. 2011;85(13):2380-2385
Nikolova, D., Krstić, J., Spasov, L., Simeonov, D., Lončarević, D., Stefanov, Pl.,& Jovanović, D. M. (2011). Surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process: N-2 sorption and XPS studies.
Russian Journal of Physical Chemistry AMaik Nauka/Interperiodica/Springer, New York., 85(13), 2380-2385.
https://doi.org/10.1134/S0036024411130188
Nikolova Dimitrinka, Krstić Jugoslav, Spasov L., Simeonov D., Lončarević Davor, Stefanov Pl., Jovanović Dušan M., "Surface properties of the Ni-silica gel catalyst precursors for the vegetable oil hydrogenation process: N-2 sorption and XPS studies" 85, no. 13 (2011):2380-2385,
https://doi.org/10.1134/S0036024411130188 .

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