In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright
TY - JOUR
AU - Mojović, Zorica
AU - Banković, Predrag
AU - Jović-Jovičić, Nataša
AU - Milutinović Nikolić, Aleksandra
AU - Abu Rabi-Stanković, Andjela S.
AU - Jovanović, Dušan M.
PY - 2011
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/810
AB - In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright
PB - Pergamon-Elsevier Science Ltd, Oxford
T2 - International Journal of Hydrogen Energy
T1 - Electrocatalytic behavior of nickel impregnated zeolite electrode
VL - 36
IS - 21
SP - 13343
EP - 13351
DO - 10.1016/j.ijhydene.2011.07.097
ER -
@article{
author = "Mojović, Zorica and Banković, Predrag and Jović-Jovičić, Nataša and Milutinović Nikolić, Aleksandra and Abu Rabi-Stanković, Andjela S. and Jovanović, Dušan M.",
year = "2011",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/810",
abstract = "In order to enhance nickel effectiveness for methanol oxidation reaction, zeolite type 13X was used as a support for nickel nanodispersion. Nickel modified samples were characterized by XRD, SEM and nitrogen adsorption-desorption measurements. The incorporation of nickel into zeolite cavities led to the partial destruction of the zeolite framework. Modified zeolite was used as the electrode material for methanol oxidation in a deaerated 0.1 M NaOH aqueous solution. It showed similar electrochemical behavior to that of polycrystalline nickel. The destruction of zeolite structure probably enabled aluminum from the framework to stabilize alpha-Ni(OH)(2). Mixture of beta- and gamma-NiOOH was obtained at the 13XNi100 electrode after cycling in alkaline solution. It was concluded from the electrochemical measurements that beta-NiOOH was preferable oxide form for methanol oxidation. Copyright",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "International Journal of Hydrogen Energy",
title = "Electrocatalytic behavior of nickel impregnated zeolite electrode",
volume = "36",
number = "21",
pages = "13343-13351",
doi = "10.1016/j.ijhydene.2011.07.097"
}
Mojović, Z., Banković, P., Jović-Jovičić, N., Milutinović Nikolić, A., Abu Rabi-Stanković, A. S.,& Jovanović, D. M. (2011). Electrocatalytic behavior of nickel impregnated zeolite electrode.
International Journal of Hydrogen Energy
Pergamon-Elsevier Science Ltd, Oxford., 36(21), 13343-13351.
https://doi.org/10.1016/j.ijhydene.2011.07.097
Mojović Z, Banković P, Jović-Jovičić N, Milutinović Nikolić A, Abu Rabi-Stanković AS, Jovanović DM. Electrocatalytic behavior of nickel impregnated zeolite electrode. International Journal of Hydrogen Energy. 2011;36(21):13343-13351
Mojović Zorica, Banković Predrag, Jović-Jovičić Nataša, Milutinović Nikolić Aleksandra, Abu Rabi-Stanković Andjela S., Jovanović Dušan M., "Electrocatalytic behavior of nickel impregnated zeolite electrode" International Journal of Hydrogen Energy, 36, no. 21 (2011):13343-13351,
https://doi.org/10.1016/j.ijhydene.2011.07.097 .
