Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn(2+) ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudosecond order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the iso...therm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.
Keywords:
Hydrogel / Kinetic model / Adsorption isotherm / Separation / Atomic force microscopy
Source:
Journal of Hazardous Materials, 2011, 192, 2, 846-854
TY - JOUR
AU - Milosavljevic, Nedeljko B.
AU - Ristic, Mirjana D.
AU - Peric-Grujic, Aleksandra A.
AU - Filipovic, Jovanka M.
AU - Štrbac, Svetlana
AU - Rakočević, Zlatko Lj.
AU - Kalagasidis Krušić, Melina
PY - 2011
UR - http://cer.ihtm.bg.ac.rs/handle/123456789/805
AB - Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn(2+) ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudosecond order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the isotherm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.
PB - Elsevier Science Bv, Amsterdam
T2 - Journal of Hazardous Materials
T1 - Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid
VL - 192
IS - 2
SP - 846
EP - 854
DO - 10.1016/j.jhazmat.2011.05.093
ER -
@article{
author = "Milosavljevic, Nedeljko B. and Ristic, Mirjana D. and Peric-Grujic, Aleksandra A. and Filipovic, Jovanka M. and Štrbac, Svetlana and Rakočević, Zlatko Lj. and Kalagasidis Krušić, Melina",
year = "2011",
url = "http://cer.ihtm.bg.ac.rs/handle/123456789/805",
abstract = "Novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid were applied as adsorbents for the removal of Zn(2+) ions from aqueous solution. In batch tests, the influence of solution pH, contact time, initial metal ion concentration and temperature was examined. The sorption was found pH dependent, pH 5.5 being the optimum value. The adsorption process was well described by the pseudosecond order kinetic. The hydrogels were characterized by spectral (Fourier transform infrared-FTIR) and structural (SEM/EDX and atomic force microscopy-AFM) analyses. The surface topography changes were observed by atomic force microscopy, while the changes in surface composition were detected using phase imaging AFM. The negative values of free energy and enthalpy indicated that the adsorption is spontaneous and exothermic one. The best fitting isotherms were Langmuir and Redlich-Peterson and it was found that both linear and nonlinear methods were appropriate for obtaining the isotherm parameters. However, the increase of temperature leads to higher adsorption capacity, since swelling degree increased with temperature.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Hazardous Materials",
title = "Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid",
volume = "192",
number = "2",
pages = "846-854",
doi = "10.1016/j.jhazmat.2011.05.093"
}
Milosavljevic, N. B., Ristic, M. D., Peric-Grujic, A. A., Filipovic, J. M., Štrbac, S., Rakočević, Z. Lj.,& Kalagasidis Krušić, M. (2011). Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid.
Journal of Hazardous Materials
Elsevier Science Bv, Amsterdam., 192(2), 846-854.
https://doi.org/10.1016/j.jhazmat.2011.05.093
Milosavljevic NB, Ristic MD, Peric-Grujic AA, Filipovic JM, Štrbac S, Rakočević ZL, Kalagasidis Krušić M. Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid. Journal of Hazardous Materials. 2011;192(2):846-854
Milosavljevic Nedeljko B., Ristic Mirjana D., Peric-Grujic Aleksandra A., Filipovic Jovanka M., Štrbac Svetlana, Rakočević Zlatko Lj., Kalagasidis Krušić Melina, "Sorption of zinc by novel pH-sensitive hydrogels based on chitosan, itaconic acid and methacrylic acid" Journal of Hazardous Materials, 192, no. 2 (2011):846-854,
https://doi.org/10.1016/j.jhazmat.2011.05.093 .
