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A mathematical model of the current density distribution in electrochemical cells

Matematički model raspodele gustine struje u elektrohemijskim ćelijama

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2011
788.pdf (454.8Kb)
Authors
Popov, Konstantin I.
Živković, Predrag M.
Nikolić, Nebojša
Article (Published version)
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Abstract
An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented.
Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.
Keywords:
current distribution / edge effect / corner effect
Source:
Journal of the Serbian Chemical Society, 2011, 76, 6, 805-822
Publisher:
  • Serbian Chemical Society
Projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)

DOI: 10.2298/JSC100312079P

ISSN: 0352-5139

WoS: 000292714000001

Scopus: 2-s2.0-79959424723
[ Google Scholar ]
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/790
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