An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented.
Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.
Keywords:
current distribution / edge effect / corner effect
Source:
Journal of the Serbian Chemical Society, 2011, 76, 6, 805-822
TY - JOUR
AU - Popov, Konstantin I.
AU - Živković, Predrag M.
AU - Nikolić, Nebojša D.
PY - 2011
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/790
AB - An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented.
AB - Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.
PB - Serbian Chemical Society
T2 - Journal of the Serbian Chemical Society
T1 - A mathematical model of the current density distribution in electrochemical cells
T1 - Matematički model raspodele gustine struje u elektrohemijskim ćelijama
VL - 76
IS - 6
SP - 805
EP - 822
DO - 10.2298/JSC100312079P
ER -
@article{
author = "Popov, Konstantin I. and Živković, Predrag M. and Nikolić, Nebojša D.",
year = "2011",
abstract = "An approach based on the equations of electrochemical kinetics for the estimation of the current density distribution in electrochemical cells is presented. This approach was employed for a theoretical explanation of the phenomena of the edge and corner effects. The effects of the geometry of the system, the kinetic parameters of the cathode reactions and the resistivity of the solution are also discussed. A procedure for a complete analysis of the current distribution in electrochemical cells is presented., Prikazan je sažeti pregled ranijih rezultata i predstavljen je poboljšan pristup proceni raspodele struje u elektrohemijskim ćelijama. Ovaj pristup, zasnovan na jednačinama elektrohemijske kinetike, upotrebljen je za teorijsko objašnjenje ivičnih i ugaonih efekata. Takođe su diskutovani uticaji geometrije sistema, kinetičkih parametara katodnih reakcija i otpornosti rastvora. Predstavljena je procedura za kompletnu analizu raspodele struje u elektrohemijskim ćelijama.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "A mathematical model of the current density distribution in electrochemical cells, Matematički model raspodele gustine struje u elektrohemijskim ćelijama",
volume = "76",
number = "6",
pages = "805-822",
doi = "10.2298/JSC100312079P"
}
Popov, K. I., Živković, P. M.,& Nikolić, N. D.. (2011). A mathematical model of the current density distribution in electrochemical cells. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 76(6), 805-822.
https://doi.org/10.2298/JSC100312079P
Popov KI, Živković PM, Nikolić ND. A mathematical model of the current density distribution in electrochemical cells. in Journal of the Serbian Chemical Society. 2011;76(6):805-822.
doi:10.2298/JSC100312079P .
Popov, Konstantin I., Živković, Predrag M., Nikolić, Nebojša D., "A mathematical model of the current density distribution in electrochemical cells" in Journal of the Serbian Chemical Society, 76, no. 6 (2011):805-822,
https://doi.org/10.2298/JSC100312079P . .
