Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex
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The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1-
(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-µ-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center.
Keywords:
Cu(II) / Girard’s T reagent / synthesis / complexes / Hydrazone Complexes / square pyramidalSource:
9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia, 2023, 69-69Publisher:
- Belgrade : Serbian Chemical Society
- Belgrade : Serbian Young Chemists’ Club
Funding / projects:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
Note:
Related info:
- Referenced by
https://cer.ihtm.bg.ac.rs/handle/123456789/7452
Institution/Community
IHTMTY - CONF AU - Savić, Milica AU - Jevtović, Mima AU - Čobeljić, Božidar AU - Anđelković, Katarina PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/7451 AB - The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1- (1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-µ-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center. PB - Belgrade : Serbian Chemical Society PB - Belgrade : Serbian Young Chemists’ Club C3 - 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia T1 - Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex SP - 69 EP - 69 UR - https://hdl.handle.net/21.15107/rcub_cer_7451 ER -
@conference{ author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Anđelković, Katarina", year = "2023", abstract = "The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1- (1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-µ-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center.", publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists’ Club", journal = "9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia", title = "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex", pages = "69-69", url = "https://hdl.handle.net/21.15107/rcub_cer_7451" }
Savić, M., Jevtović, M., Čobeljić, B.,& Anđelković, K.. (2023). Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex. in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia Belgrade : Serbian Chemical Society., 69-69. https://hdl.handle.net/21.15107/rcub_cer_7451
Savić M, Jevtović M, Čobeljić B, Anđelković K. Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex. in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia. 2023;:69-69. https://hdl.handle.net/21.15107/rcub_cer_7451 .
Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Anđelković, Katarina, "Synthesis and characterization of binuclear azide-bridged hydrazone Cu(II) complex" in 9th Conference of Young Chemists of Serbia, Book of abstracts, 4th November 2023, Novi Sad, Serbia (2023):69-69, https://hdl.handle.net/21.15107/rcub_cer_7451 .