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Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range

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2010
723.pdf (228.9Kb)
Authors
Nikolić, Nebojša D.
Article (Published version)
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Abstract
This a review paper considering fundamental aspects of copper electrodeposition at high overpotentials where parallel to copper electrodeposition, hydrogen evolution reaction occurs. The two types of copper deposits are formed in the hydrogen co-deposition range: (a) the open and porous structures denoted as the honeycomb-like ones, and (b) powdered deposits. Phenomenology of the formation of the honeycomb-like structure, as well as factors affecting the formation of this type of structure are described in detail. The increase of the specific surface area of the honeycomb-like structure by the application of the periodically changing regimes of electrolysis, such as pulsating overpotential (PO) regime is considered. Correlation between the shape of copper powder particles and the quantity of evolved hydrogen by which they are formed was also presented.
Ovo je pregledni rad koji razmatra fundamentalne aspekte elektrohemijskog taloženja bakra na visokim prenapetostima gde paralelno procesu elektrohemijskog taloženja bakra se odigrava reakcija izdvajanja vodonika. Dva tipa taloga bakra su formirana u oblasti ko-depozicije vodonika: (a) otvorene i porozne strukture označene kao strukture pčelinjeg saća, i (b) praškasti talozi. Fenomenologija formiranja strukture pčelinjeg saća, kao i faktori koji utiču na formiranje ovog tipa strukture su detaljno opisani. Povećanje specifične površine strukture pčelinjeg saća primenom periodično promenljivih režima elektrolize, kao što je režim pulsirajuće prenapetosti (PP), je razmatran. Uzajamna veza između oblika čestica praha i količine vodonika izdvojene tokom njihovog formiranja je takođe predstavljena.
Source:
Zaštita materijala, 2010, 51, 4, 197-203
Publisher:
  • Belgrade, Serbia : Engineering Society for Corrosion
Funding / projects:
  • Deposition of ultrafinepowders of metals and alloys and nanostructured surfaces by electrochemical techniques (RS-142032)

ISSN: 0351-9465

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_cer_725
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/725
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Nikolić, Nebojša D.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/725
AB  - This a review paper considering fundamental aspects of copper electrodeposition at high overpotentials where parallel to copper electrodeposition, hydrogen evolution reaction occurs. The two types of copper deposits are formed in the hydrogen co-deposition range: (a) the open and porous structures denoted as the honeycomb-like ones, and (b) powdered deposits. Phenomenology of the formation of the honeycomb-like structure, as well as factors affecting the formation of this type of structure are described in detail. The increase of the specific surface area of the honeycomb-like structure by the application of the periodically changing regimes of electrolysis, such as pulsating overpotential (PO) regime is considered. Correlation between the shape of copper powder particles and the quantity of evolved hydrogen by which they are formed was also presented.
AB  - Ovo je pregledni rad koji razmatra fundamentalne aspekte elektrohemijskog taloženja bakra na visokim prenapetostima gde paralelno procesu elektrohemijskog taloženja bakra se odigrava reakcija izdvajanja vodonika. Dva tipa taloga bakra su formirana u oblasti ko-depozicije vodonika: (a) otvorene i porozne strukture označene kao strukture pčelinjeg saća, i (b) praškasti talozi. Fenomenologija formiranja strukture pčelinjeg saća, kao i faktori koji utiču na formiranje ovog tipa strukture su detaljno opisani. Povećanje specifične površine strukture pčelinjeg saća primenom periodično promenljivih režima elektrolize, kao što je režim pulsirajuće prenapetosti (PP), je razmatran. Uzajamna veza između oblika čestica praha i količine vodonika izdvojene tokom njihovog formiranja je takođe predstavljena.
PB  - Belgrade, Serbia : Engineering Society for Corrosion
T2  - Zaštita materijala
T1  - Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range
VL  - 51
IS  - 4
SP  - 197
EP  - 203
UR  - https://hdl.handle.net/21.15107/rcub_cer_725
ER  - 
@article{
author = "Nikolić, Nebojša D.",
year = "2010",
abstract = "This a review paper considering fundamental aspects of copper electrodeposition at high overpotentials where parallel to copper electrodeposition, hydrogen evolution reaction occurs. The two types of copper deposits are formed in the hydrogen co-deposition range: (a) the open and porous structures denoted as the honeycomb-like ones, and (b) powdered deposits. Phenomenology of the formation of the honeycomb-like structure, as well as factors affecting the formation of this type of structure are described in detail. The increase of the specific surface area of the honeycomb-like structure by the application of the periodically changing regimes of electrolysis, such as pulsating overpotential (PO) regime is considered. Correlation between the shape of copper powder particles and the quantity of evolved hydrogen by which they are formed was also presented., Ovo je pregledni rad koji razmatra fundamentalne aspekte elektrohemijskog taloženja bakra na visokim prenapetostima gde paralelno procesu elektrohemijskog taloženja bakra se odigrava reakcija izdvajanja vodonika. Dva tipa taloga bakra su formirana u oblasti ko-depozicije vodonika: (a) otvorene i porozne strukture označene kao strukture pčelinjeg saća, i (b) praškasti talozi. Fenomenologija formiranja strukture pčelinjeg saća, kao i faktori koji utiču na formiranje ovog tipa strukture su detaljno opisani. Povećanje specifične površine strukture pčelinjeg saća primenom periodično promenljivih režima elektrolize, kao što je režim pulsirajuće prenapetosti (PP), je razmatran. Uzajamna veza između oblika čestica praha i količine vodonika izdvojene tokom njihovog formiranja je takođe predstavljena.",
publisher = "Belgrade, Serbia : Engineering Society for Corrosion",
journal = "Zaštita materijala",
title = "Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range",
volume = "51",
number = "4",
pages = "197-203",
url = "https://hdl.handle.net/21.15107/rcub_cer_725"
}
Nikolić, N. D.. (2010). Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range. in Zaštita materijala
Belgrade, Serbia : Engineering Society for Corrosion., 51(4), 197-203.
https://hdl.handle.net/21.15107/rcub_cer_725
Nikolić ND. Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range. in Zaštita materijala. 2010;51(4):197-203.
https://hdl.handle.net/21.15107/rcub_cer_725 .
Nikolić, Nebojša D., "Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range" in Zaštita materijala, 51, no. 4 (2010):197-203,
https://hdl.handle.net/21.15107/rcub_cer_725 .

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