Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range
Abstract
This a review paper considering fundamental aspects of copper electrodeposition at high overpotentials where parallel to copper electrodeposition, hydrogen evolution reaction occurs. The two types of copper deposits are formed in the hydrogen co-deposition range: (a) the open and porous structures denoted as the honeycomb-like ones, and (b) powdered deposits. Phenomenology of the formation of the honeycomb-like structure, as well as factors affecting the formation of this type of structure are described in detail. The increase of the specific surface area of the honeycomb-like structure by the application of the periodically changing regimes of electrolysis, such as pulsating overpotential (PO) regime is considered. Correlation between the shape of copper powder particles and the quantity of evolved hydrogen by which they are formed was also presented.
Ovo je pregledni rad koji razmatra fundamentalne aspekte elektrohemijskog taloženja bakra na visokim prenapetostima gde paralelno procesu elektrohemijskog taloženja bakra se odigrava reakcija izdvajanja vodonika. Dva tipa taloga bakra su formirana u oblasti ko-depozicije vodonika: (a) otvorene i porozne strukture označene kao strukture pčelinjeg saća, i (b) praškasti talozi. Fenomenologija formiranja strukture pčelinjeg saća, kao i faktori koji utiču na formiranje ovog tipa strukture su detaljno opisani. Povećanje specifične površine strukture pčelinjeg saća primenom periodično promenljivih režima elektrolize, kao što je režim pulsirajuće prenapetosti (PP), je razmatran. Uzajamna veza između oblika čestica praha i količine vodonika izdvojene tokom njihovog formiranja je takođe predstavljena.
Source:
Zaštita materijala, 2010, 51, 4, 197-203Publisher:
- Belgrade, Serbia : Engineering Society for Corrosion
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IHTMTY - JOUR AU - Nikolić, Nebojša D. PY - 2010 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/725 AB - This a review paper considering fundamental aspects of copper electrodeposition at high overpotentials where parallel to copper electrodeposition, hydrogen evolution reaction occurs. The two types of copper deposits are formed in the hydrogen co-deposition range: (a) the open and porous structures denoted as the honeycomb-like ones, and (b) powdered deposits. Phenomenology of the formation of the honeycomb-like structure, as well as factors affecting the formation of this type of structure are described in detail. The increase of the specific surface area of the honeycomb-like structure by the application of the periodically changing regimes of electrolysis, such as pulsating overpotential (PO) regime is considered. Correlation between the shape of copper powder particles and the quantity of evolved hydrogen by which they are formed was also presented. AB - Ovo je pregledni rad koji razmatra fundamentalne aspekte elektrohemijskog taloženja bakra na visokim prenapetostima gde paralelno procesu elektrohemijskog taloženja bakra se odigrava reakcija izdvajanja vodonika. Dva tipa taloga bakra su formirana u oblasti ko-depozicije vodonika: (a) otvorene i porozne strukture označene kao strukture pčelinjeg saća, i (b) praškasti talozi. Fenomenologija formiranja strukture pčelinjeg saća, kao i faktori koji utiču na formiranje ovog tipa strukture su detaljno opisani. Povećanje specifične površine strukture pčelinjeg saća primenom periodično promenljivih režima elektrolize, kao što je režim pulsirajuće prenapetosti (PP), je razmatran. Uzajamna veza između oblika čestica praha i količine vodonika izdvojene tokom njihovog formiranja je takođe predstavljena. PB - Belgrade, Serbia : Engineering Society for Corrosion T2 - Zaštita materijala T1 - Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range VL - 51 IS - 4 SP - 197 EP - 203 UR - https://hdl.handle.net/21.15107/rcub_cer_725 ER -
@article{ author = "Nikolić, Nebojša D.", year = "2010", abstract = "This a review paper considering fundamental aspects of copper electrodeposition at high overpotentials where parallel to copper electrodeposition, hydrogen evolution reaction occurs. The two types of copper deposits are formed in the hydrogen co-deposition range: (a) the open and porous structures denoted as the honeycomb-like ones, and (b) powdered deposits. Phenomenology of the formation of the honeycomb-like structure, as well as factors affecting the formation of this type of structure are described in detail. The increase of the specific surface area of the honeycomb-like structure by the application of the periodically changing regimes of electrolysis, such as pulsating overpotential (PO) regime is considered. Correlation between the shape of copper powder particles and the quantity of evolved hydrogen by which they are formed was also presented., Ovo je pregledni rad koji razmatra fundamentalne aspekte elektrohemijskog taloženja bakra na visokim prenapetostima gde paralelno procesu elektrohemijskog taloženja bakra se odigrava reakcija izdvajanja vodonika. Dva tipa taloga bakra su formirana u oblasti ko-depozicije vodonika: (a) otvorene i porozne strukture označene kao strukture pčelinjeg saća, i (b) praškasti talozi. Fenomenologija formiranja strukture pčelinjeg saća, kao i faktori koji utiču na formiranje ovog tipa strukture su detaljno opisani. Povećanje specifične površine strukture pčelinjeg saća primenom periodično promenljivih režima elektrolize, kao što je režim pulsirajuće prenapetosti (PP), je razmatran. Uzajamna veza između oblika čestica praha i količine vodonika izdvojene tokom njihovog formiranja je takođe predstavljena.", publisher = "Belgrade, Serbia : Engineering Society for Corrosion", journal = "Zaštita materijala", title = "Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range", volume = "51", number = "4", pages = "197-203", url = "https://hdl.handle.net/21.15107/rcub_cer_725" }
Nikolić, N. D.. (2010). Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range. in Zaštita materijala Belgrade, Serbia : Engineering Society for Corrosion., 51(4), 197-203. https://hdl.handle.net/21.15107/rcub_cer_725
Nikolić ND. Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range. in Zaštita materijala. 2010;51(4):197-203. https://hdl.handle.net/21.15107/rcub_cer_725 .
Nikolić, Nebojša D., "Fundamental aspects of copper electrodeposition in the hydrogen Co-deposition range" in Zaštita materijala, 51, no. 4 (2010):197-203, https://hdl.handle.net/21.15107/rcub_cer_725 .