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A Copper(II) Ion-Selective Potentiometric Sensor Based on N ',N ',N '',N '''-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix

Authorized Users Only
2010
Authors
Petković, Branka B.
Sovilj, Sofija P.
Budimir, Milana V.
Simonović, Ranko M.
Jovanović, Vladislava M.
Article (Published version)
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Abstract
The simple PVC-based membrane containing N',N',N '',N '''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) as an ionophore and dibutyl phthalate as a plasticizer, directly coated on a glassy carbon electrode was examined as a new sensor for Cu2+ ions. The potential response was linear within the concentration range of 1.0x10(-1)-1.0 x 10(-6)M with a Nernstian slope of 28.8 mV/decade and detection limit of 7.0 x 10(-7)M. The electrode was used in aqueous solutions over a wide pH range (1.3-6). The sensor exhibited excellent selectivity for Cu2+ ion over a number of cations and was successfully used in its determination in real samples.
Keywords:
Cu(II) potentiometric sensors / Coated glassy carbon rod / Ionophore / N ',N ',N '',N '''-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane / Waste waters
Source:
Electroanalysis, 2010, 22, 16, 1894-1900
Publisher:
  • Wiley-Blackwell, Malden
Funding / projects:
  • Razvoj novih analitičkih metoda i njihova primena za određivanje sadržaja teških metala u različitim uzorcima životne sredine (RS-142079)

DOI: 10.1002/elan.201000053

ISSN: 1040-0397

WoS: 000281489000014

Scopus: 2-s2.0-77955963495
[ Google Scholar ]
24
22
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/695
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Petković, Branka B.
AU  - Sovilj, Sofija P.
AU  - Budimir, Milana V.
AU  - Simonović, Ranko M.
AU  - Jovanović, Vladislava M.
PY  - 2010
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/695
AB  - The simple PVC-based membrane containing N',N',N '',N '''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) as an ionophore and dibutyl phthalate as a plasticizer, directly coated on a glassy carbon electrode was examined as a new sensor for Cu2+ ions. The potential response was linear within the concentration range of 1.0x10(-1)-1.0 x 10(-6)M with a Nernstian slope of 28.8 mV/decade and detection limit of 7.0 x 10(-7)M. The electrode was used in aqueous solutions over a wide pH range (1.3-6). The sensor exhibited excellent selectivity for Cu2+ ion over a number of cations and was successfully used in its determination in real samples.
PB  - Wiley-Blackwell, Malden
T2  - Electroanalysis
T1  - A Copper(II) Ion-Selective Potentiometric Sensor Based on N ',N ',N '',N '''-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix
VL  - 22
IS  - 16
SP  - 1894
EP  - 1900
DO  - 10.1002/elan.201000053
ER  - 
@article{
author = "Petković, Branka B. and Sovilj, Sofija P. and Budimir, Milana V. and Simonović, Ranko M. and Jovanović, Vladislava M.",
year = "2010",
abstract = "The simple PVC-based membrane containing N',N',N '',N '''-tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane (tpmc) as an ionophore and dibutyl phthalate as a plasticizer, directly coated on a glassy carbon electrode was examined as a new sensor for Cu2+ ions. The potential response was linear within the concentration range of 1.0x10(-1)-1.0 x 10(-6)M with a Nernstian slope of 28.8 mV/decade and detection limit of 7.0 x 10(-7)M. The electrode was used in aqueous solutions over a wide pH range (1.3-6). The sensor exhibited excellent selectivity for Cu2+ ion over a number of cations and was successfully used in its determination in real samples.",
publisher = "Wiley-Blackwell, Malden",
journal = "Electroanalysis",
title = "A Copper(II) Ion-Selective Potentiometric Sensor Based on N ',N ',N '',N '''-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix",
volume = "22",
number = "16",
pages = "1894-1900",
doi = "10.1002/elan.201000053"
}
Petković, B. B., Sovilj, S. P., Budimir, M. V., Simonović, R. M.,& Jovanović, V. M.. (2010). A Copper(II) Ion-Selective Potentiometric Sensor Based on N ',N ',N '',N '''-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix. in Electroanalysis
Wiley-Blackwell, Malden., 22(16), 1894-1900.
https://doi.org/10.1002/elan.201000053
Petković BB, Sovilj SP, Budimir MV, Simonović RM, Jovanović VM. A Copper(II) Ion-Selective Potentiometric Sensor Based on N ',N ',N '',N '''-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix. in Electroanalysis. 2010;22(16):1894-1900.
doi:10.1002/elan.201000053 .
Petković, Branka B., Sovilj, Sofija P., Budimir, Milana V., Simonović, Ranko M., Jovanović, Vladislava M., "A Copper(II) Ion-Selective Potentiometric Sensor Based on N ',N ',N '',N '''-Tetrakis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane in PVC Matrix" in Electroanalysis, 22, no. 16 (2010):1894-1900,
https://doi.org/10.1002/elan.201000053 . .

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