Co supported chitosan-derived carbon-smectite catalyst in Oxone® induced at dye degradation
Аутори
Stevanović, GordanaJović-Jovičić, Nataša
Popović, Aleksandar
Dojčinović, Biljana
Milutinović Nikolić, Aleksandra
Banković, Predrag
Ajduković, Marija
Чланак у часопису (Рецензирана верзија)
Метаподаци
Приказ свих података о документуАпстракт
Catalytic degradation of tartrazine in the presence of Oxone® activated by a catalyst constituted of cobalt supported on a nanocomposite of smectite with chitosan-derived carbon was investigated. The catalyst was synthesized using cobalt impregnation followed by carbonization at 773 K in an inert atmosphere. The synthesized catalyst was previously fully characterized using appropriate characterization methods, including XRPD, XPS, FTIR, HR-TEM, and low-temperature N2-physisorption analysis. The catalytic experiments were performed by varying different experimental parameters (dye concentration, Oxone® concentration, temperature, and initial pH of the reaction solution). The kinetic and thermodynamic parameters were estimated from the experimental results. The kinetics data showed the best fit with the pseudo-first-order kinetics model. The activation energy of the investigated degradation process was calculated according to the Arrhenius equation. The catalyst showed excellent performa...nce at low temperatures even at 298 K, and in the wide range of pH values.
Кључне речи:
Tartrazine degradation / Smectite / Oxone® activation / KineticsИзвор:
Science of Sintering, 2023Издавач:
- Serbian Ceramic Society
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
Институција/група
IHTMTY - JOUR AU - Stevanović, Gordana AU - Jović-Jovičić, Nataša AU - Popović, Aleksandar AU - Dojčinović, Biljana AU - Milutinović Nikolić, Aleksandra AU - Banković, Predrag AU - Ajduković, Marija PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6902 AB - Catalytic degradation of tartrazine in the presence of Oxone® activated by a catalyst constituted of cobalt supported on a nanocomposite of smectite with chitosan-derived carbon was investigated. The catalyst was synthesized using cobalt impregnation followed by carbonization at 773 K in an inert atmosphere. The synthesized catalyst was previously fully characterized using appropriate characterization methods, including XRPD, XPS, FTIR, HR-TEM, and low-temperature N2-physisorption analysis. The catalytic experiments were performed by varying different experimental parameters (dye concentration, Oxone® concentration, temperature, and initial pH of the reaction solution). The kinetic and thermodynamic parameters were estimated from the experimental results. The kinetics data showed the best fit with the pseudo-first-order kinetics model. The activation energy of the investigated degradation process was calculated according to the Arrhenius equation. The catalyst showed excellent performance at low temperatures even at 298 K, and in the wide range of pH values. PB - Serbian Ceramic Society T2 - Science of Sintering T1 - Co supported chitosan-derived carbon-smectite catalyst in Oxone® induced at dye degradation DO - 10.2298/SOS230427037S ER -
@article{ author = "Stevanović, Gordana and Jović-Jovičić, Nataša and Popović, Aleksandar and Dojčinović, Biljana and Milutinović Nikolić, Aleksandra and Banković, Predrag and Ajduković, Marija", year = "2023", abstract = "Catalytic degradation of tartrazine in the presence of Oxone® activated by a catalyst constituted of cobalt supported on a nanocomposite of smectite with chitosan-derived carbon was investigated. The catalyst was synthesized using cobalt impregnation followed by carbonization at 773 K in an inert atmosphere. The synthesized catalyst was previously fully characterized using appropriate characterization methods, including XRPD, XPS, FTIR, HR-TEM, and low-temperature N2-physisorption analysis. The catalytic experiments were performed by varying different experimental parameters (dye concentration, Oxone® concentration, temperature, and initial pH of the reaction solution). The kinetic and thermodynamic parameters were estimated from the experimental results. The kinetics data showed the best fit with the pseudo-first-order kinetics model. The activation energy of the investigated degradation process was calculated according to the Arrhenius equation. The catalyst showed excellent performance at low temperatures even at 298 K, and in the wide range of pH values.", publisher = "Serbian Ceramic Society", journal = "Science of Sintering", title = "Co supported chitosan-derived carbon-smectite catalyst in Oxone® induced at dye degradation", doi = "10.2298/SOS230427037S" }
Stevanović, G., Jović-Jovičić, N., Popović, A., Dojčinović, B., Milutinović Nikolić, A., Banković, P.,& Ajduković, M.. (2023). Co supported chitosan-derived carbon-smectite catalyst in Oxone® induced at dye degradation. in Science of Sintering Serbian Ceramic Society.. https://doi.org/10.2298/SOS230427037S
Stevanović G, Jović-Jovičić N, Popović A, Dojčinović B, Milutinović Nikolić A, Banković P, Ajduković M. Co supported chitosan-derived carbon-smectite catalyst in Oxone® induced at dye degradation. in Science of Sintering. 2023;. doi:10.2298/SOS230427037S .
Stevanović, Gordana, Jović-Jovičić, Nataša, Popović, Aleksandar, Dojčinović, Biljana, Milutinović Nikolić, Aleksandra, Banković, Predrag, Ajduković, Marija, "Co supported chitosan-derived carbon-smectite catalyst in Oxone® induced at dye degradation" in Science of Sintering (2023), https://doi.org/10.2298/SOS230427037S . .