Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent"
Authors
Savić, Milica
Jevtović, Mima

Zlatar, Matija

Gruden, Maja

Mitić, Dragana

Čobeljić, Božidar

Anđelković, Katarina

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The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.
Keywords:
synthesis / characterization / 2-acetylpyridine / Girard’s P reagent / Ni(III) / DFTSource:
2023Publisher:
- Belgrade, Serbia : Materials Research Society of Serbia
Funding / projects:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-7750288)
Note:
- Poster P.S.40 presented at: Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro
- Abstract: https://cer.ihtm.bg.ac.rs/handle/123456789/6608
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https://cer.ihtm.bg.ac.rs/handle/123456789/6608
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IHTMTY - CONF AU - Savić, Milica AU - Jevtović, Mima AU - Zlatar, Matija AU - Gruden, Maja AU - Mitić, Dragana AU - Čobeljić, Božidar AU - Anđelković, Katarina PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6609 AB - The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex. PB - Belgrade, Serbia : Materials Research Society of Serbia T1 - Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent" UR - https://hdl.handle.net/21.15107/rcub_cer_6609 ER -
@conference{ author = "Savić, Milica and Jevtović, Mima and Zlatar, Matija and Gruden, Maja and Mitić, Dragana and Čobeljić, Božidar and Anđelković, Katarina", year = "2023", abstract = "The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.", publisher = "Belgrade, Serbia : Materials Research Society of Serbia", title = "Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent"", url = "https://hdl.handle.net/21.15107/rcub_cer_6609" }
Savić, M., Jevtović, M., Zlatar, M., Gruden, M., Mitić, D., Čobeljić, B.,& Anđelković, K.. (2023). Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent". Belgrade, Serbia : Materials Research Society of Serbia.. https://hdl.handle.net/21.15107/rcub_cer_6609
Savić M, Jevtović M, Zlatar M, Gruden M, Mitić D, Čobeljić B, Anđelković K. Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent". 2023;. https://hdl.handle.net/21.15107/rcub_cer_6609 .
Savić, Milica, Jevtović, Mima, Zlatar, Matija, Gruden, Maja, Mitić, Dragana, Čobeljić, Božidar, Anđelković, Katarina, "Poster presentation: "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent"" (2023), https://hdl.handle.net/21.15107/rcub_cer_6609 .