Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent
Аутори
Savić, MilicaJevtović, Mima
Zlatar, Matija
Gruden, Maja
Mitić, Dragana
Čobeljić, Božidar
Anđelković, Katarina
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand
with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water
mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The
tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion
through NNO set of donor atoms forming two five-membered chelate rings and the other three
coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was
characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was
defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis.
DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.
Кључне речи:
synthesis / characterization / 2-acetylpyridine / Girard’s P reagent / Ni(III) / DFTИзвор:
Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro, 2023, 114-114Издавач:
- Belgrade, Serbia : Materials Research Society of Serbia
Финансирање / пројекти:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
Напомена:
- Poster: P.S.40
- Poster: https://cer.ihtm.bg.ac.rs/handle/123456789/6609
Повезане информације:
- Повезани садржај
https://cer.ihtm.bg.ac.rs/handle/123456789/6609
Институција/група
IHTMTY - CONF AU - Savić, Milica AU - Jevtović, Mima AU - Zlatar, Matija AU - Gruden, Maja AU - Mitić, Dragana AU - Čobeljić, Božidar AU - Anđelković, Katarina PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6608 AB - The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex. PB - Belgrade, Serbia : Materials Research Society of Serbia C3 - Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro T1 - Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent SP - 114 EP - 114 UR - https://hdl.handle.net/21.15107/rcub_cer_6608 ER -
@conference{ author = "Savić, Milica and Jevtović, Mima and Zlatar, Matija and Gruden, Maja and Mitić, Dragana and Čobeljić, Božidar and Anđelković, Katarina", year = "2023", abstract = "The ligand (HLCl) was synthetized by the reaction of 2-acetylpyridine and Girard’s P reagent in molar ratio 1 : 1 in ethanol (1–2 drops of cc. HCl were added). The reaction of hydrazone ligand with the metal salt Ni(BF4)2·6H2O and NaN3 in a molar ratio 1:1:4 in methanol/acetonitrile/water mixture results in the formation of Ni(III) complex with composition [NiL(N3)3]. The tridentate ligand (HLCl) is coordinated in deprotonated, formally neutral, form to the nickel ion through NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are occupied by meridionally coordinated azide anions. The ligand (HLCl) was characterized by elemental analysis, IR and NMR spectroscopy and structure of the complex was defined by X-ray analysis, IR and EPR spectroscopy, molar conductivity and elemental analysis. DFT calculations were performed to determine stability and rationalise formation of Ni(III) complex.", publisher = "Belgrade, Serbia : Materials Research Society of Serbia", journal = "Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro", title = "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent", pages = "114-114", url = "https://hdl.handle.net/21.15107/rcub_cer_6608" }
Savić, M., Jevtović, M., Zlatar, M., Gruden, M., Mitić, D., Čobeljić, B.,& Anđelković, K.. (2023). Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent. in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro Belgrade, Serbia : Materials Research Society of Serbia., 114-114. https://hdl.handle.net/21.15107/rcub_cer_6608
Savić M, Jevtović M, Zlatar M, Gruden M, Mitić D, Čobeljić B, Anđelković K. Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent. in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro. 2023;:114-114. https://hdl.handle.net/21.15107/rcub_cer_6608 .
Savić, Milica, Jevtović, Mima, Zlatar, Matija, Gruden, Maja, Mitić, Dragana, Čobeljić, Božidar, Anđelković, Katarina, "Synthesis and characterization of Ni(III) complex with condensation product of 2-acetylpyridine and Girard’s P reagent" in Twenty-fourth Annual Conference ‘’YUCOMAT 2023’’, Program and Book of Abstracts, September 4–8, 2023, Herceg Novi, Montenegro (2023):114-114, https://hdl.handle.net/21.15107/rcub_cer_6608 .