Show simple item record

dc.creatorHusinec, Suren
dc.creatorJadranin, Milka
dc.creatorMarković, Rade
dc.creatorPetkovic, Milos
dc.creatorSavić, Vladimir
dc.creatorTodorović, Nina
dc.date.accessioned2019-01-30T17:22:38Z
dc.date.available2019-01-30T17:22:38Z
dc.date.issued2010
dc.identifier.issn0040-4039
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/643
dc.description.abstractAllyl acetates were synthesised from allenes utilising methodology based on the general reactivity of pi-allyl palladium intermediates which participate efficiently in transformations involving nucleophiles. Reactions of allenes and aryl iodides in the presence of AcONa and Pd(OAc)(2)/PPh(3) as the catalytic system afforded allyl acetates in moderate to good yields. Monosubstituted allenes, depending on their structure, produced either a separable mixture of two regioisomeric products or a single regioisomer. As allylic acetates can be easily hydrolysed, the methodology is applicable for the synthesis of allyl alcohols as well.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142071/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142072/RS//
dc.rightsrestrictedAccess
dc.sourceTetrahedron Letters
dc.titlePalladium-catalysed synthesis of allyl acetates from allenesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractСавиц, Владимир; Марковиц, Раде; Тодоровић, Нина; Јадранин, Милка; Хусинец, Сурен; Петковиц, Милос;
dc.citation.volume51
dc.citation.issue31
dc.citation.spage4066
dc.citation.epage4068
dc.citation.other51(31): 4066-4068
dc.citation.rankM22
dc.identifier.doi10.1016/j.tetlet.2010.05.136
dc.identifier.rcubConv_2531
dc.identifier.scopus2-s2.0-77954031310
dc.identifier.wos000280053600018
dc.type.versionpublishedVersion


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record