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Palladium-catalysed synthesis of allyl acetates from allenes
dc.creator | Husinec, Suren | |
dc.creator | Jadranin, Milka | |
dc.creator | Marković, Rade | |
dc.creator | Petkovic, Milos | |
dc.creator | Savić, Vladimir | |
dc.creator | Todorović, Nina | |
dc.date.accessioned | 2019-01-30T17:22:38Z | |
dc.date.available | 2019-01-30T17:22:38Z | |
dc.date.issued | 2010 | |
dc.identifier.issn | 0040-4039 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/643 | |
dc.description.abstract | Allyl acetates were synthesised from allenes utilising methodology based on the general reactivity of pi-allyl palladium intermediates which participate efficiently in transformations involving nucleophiles. Reactions of allenes and aryl iodides in the presence of AcONa and Pd(OAc)(2)/PPh(3) as the catalytic system afforded allyl acetates in moderate to good yields. Monosubstituted allenes, depending on their structure, produced either a separable mixture of two regioisomeric products or a single regioisomer. As allylic acetates can be easily hydrolysed, the methodology is applicable for the synthesis of allyl alcohols as well. | en |
dc.publisher | Oxford : Pergamon-Elsevier Science Ltd | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142071/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142072/RS// | |
dc.rights | restrictedAccess | |
dc.source | Tetrahedron Letters | |
dc.title | Palladium-catalysed synthesis of allyl acetates from allenes | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Савиц, Владимир; Марковиц, Раде; Тодоровић, Нина; Јадранин, Милка; Хусинец, Сурен; Петковиц, Милос; | |
dc.citation.volume | 51 | |
dc.citation.issue | 31 | |
dc.citation.spage | 4066 | |
dc.citation.epage | 4068 | |
dc.citation.other | 51(31): 4066-4068 | |
dc.citation.rank | M22 | |
dc.identifier.doi | 10.1016/j.tetlet.2010.05.136 | |
dc.identifier.scopus | 2-s2.0-77954031310 | |
dc.identifier.wos | 000280053600018 | |
dc.type.version | publishedVersion |