Show simple item record

dc.creatorKrstić, Natalija
dc.creatorBjelaković, Mira
dc.creatorDabović, Milan
dc.creatorPavlović, Vladimir D.
dc.date.accessioned2019-01-30T17:22:17Z
dc.date.available2019-01-30T17:22:17Z
dc.date.issued2010
dc.identifier.issn1420-3049
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/629
dc.description.abstractThe reactions of selected alpha,beta-unsaturated steroidal ketones with Lawesson's reagent (LR) in CH(2)Cl(2) and toluene under the standard reaction conditions and with a combination of phosphorus pentasulfide with hexamethyldisiloxane (P(4)S(10)/HMDO) in 1,2-dichlorobenzene (ODCB) under microwave irradiation were investigated and for this purpose several cholestane, androstane and pregnane carbonyl derivatives were chosen. Depending on the reagent and the solvent, 19 new sulfur containing compounds, including dithiones 4c and 4d, alpha,beta-unsaturated 3-thiones 3a-e, dimer-sulfides 2a-e, 1,2,4-trithiolanes 5a-e and phosphonotrithioates 6b-e were synthesized. All newly prepared compounds were characterized by IR, (1)H- and (13)C-NMR spectroscopy and elemental analysis.en
dc.publisherMDPI AG
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142033/RS//
dc.rightsopenAccess
dc.sourceMolecules
dc.subjectalpha,beta-unsaturated steroidal ketonesen
dc.subjectalpha,beta-unsaturated 3-thionesen
dc.subjectLawesson's reagenten
dc.subjectP(4)S(10)/HMDOen
dc.subjectdimerizationen
dc.subjectmicrowave irradiationen
dc.titleThionation of Some alpha,beta-Unsaturated Steroidal Ketonesen
dc.typearticle
dc.rights.licenseBY
dcterms.abstractДабовиц, Милан М.; Бјелаковић, Мира; Павловиц, Владимир Д.; Крстић, Наталија;
dc.citation.volume15
dc.citation.issue5
dc.citation.spage3462
dc.citation.epage3477
dc.citation.other15(5): 3462-3477
dc.citation.rankM22
dc.identifier.pmid20657494
dc.identifier.doi10.3390/molecules15053462
dc.identifier.rcubConv_2515
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/9257/627.pdf
dc.identifier.scopus2-s2.0-77952859278
dc.identifier.wos000278105400039
dc.type.versionpublishedVersion


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record