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Neočekivani Ni(III) komleks sa hidrazonskim ligandom – analiza spinskih stanja

dc.creatorMilčić, Miloš
dc.creatorGruden, Maja
dc.creatorZlatar, Matija
dc.date.accessioned2023-06-06T10:04:51Z
dc.date.available2023-06-06T10:04:51Z
dc.date.issued2023
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/6230
dc.description.abstractDuring synthesis of Ni(II) complex with (E)−1-(2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethyl)pyridin-1-ium ligand (L) unexpected oxidation of Ni(II) to Ni(III) with atmospheric oxygen occurred at mild conditions. Unusual spin and magnetic properties of the synthesized octahedral [NiL(N3)3] complex, were further investigated with Density Functional Theory (DFT) methods.sr
dc.description.abstractTokom sinteze kompleksa nikla(II) sa tridentatnim I−1-(2-okso-2-(2-(1-(piridin-2-il)etiliden)hydrazinil)etil)piridin-1-ijum ligandom (L) došlo je do neočekivane oksidacije Ni(II) u Ni(III), vazdušnim kiseonikom, pri veoma blagim uslovima. Nastali oktaedarski [NiL(N3)3] kompleks pokazuje veoma zanimljive spinske i magnetne osobine, koje su proučavane metodama teorije funkcionala gustine (DFT).sr
dc.language.isosrsr
dc.language.isoensr
dc.publisherTMMagCat projectsr
dc.relationinfo:eu-repo/grantAgreement/ScienceFundRS/Ideje/7750288/RS//sr
dc.relation.isreferencedbyhttps://cer.ihtm.bg.ac.rs/handle/123456789/6210
dc.rightsopenAccesssr
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectDFTsr
dc.subjectoctahedral complexessr
dc.subjecttransition metal complexessr
dc.subjectsynthesissr
dc.subjectNi(II)sr
dc.subjectNi(III)sr
dc.subjectspin statessr
dc.subjectmagnetic propertiessr
dc.subjectspin densitysr
dc.titleUnexpected Ni(III) complex with hydrazone lignad – spin state analysissr
dc.titleNeočekivani Ni(III) komleks sa hidrazonskim ligandom – analiza spinskih stanjasr
dc.typeconferenceObjectsr
dc.rights.licenseBYsr
dc.description.otherPoster presented at: 59th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 01-02, 2023.
dc.description.otherAbstract: [https://cer.ihtm.bg.ac.rs/handle/123456789/6210]
dc.identifier.rcubhttps://hdl.handle.net/21.15107/rcub_cer_6230
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs/bitstream/id/25666/MilosSHD.pdf
dc.type.versionpublishedVersionsr


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