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dc.creatorKhristova, M.S.
dc.creatorPetrović, Srđan
dc.creatorTerlecki-Baričević, Ana V.
dc.creatorMehandjiev, D.R.
dc.date.accessioned2019-01-30T17:22:07Z
dc.date.available2019-01-30T17:22:07Z
dc.date.issued2009
dc.identifier.issn1895-1066
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/621
dc.description.abstractThe perovskite type oxides (nominal formula LaTi0.5 Mg0.5O3) with addition of Pd were prepared by annealing the ethanol solution of precursors in nitrogen flow at 1200°C and characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and temperature programmed desorption of NO (NO-TPD). Their activity was evaluated for NO reduction by CO under stoichiometric and oxidizing conditions and for direct decomposition of NO. Pd substituted samples exhibited high NO reduction activity and selectivity towards N2. Nearly complete elimination of NO was achieved at 200°C. Two simultaneous reactions, NO reduction by CO and direct decomposition of NO as well as two forms of NO adsorption were observed on the surface of Pd substituted perovskite samples. The distribution of Pd in different catalytically active sites or complexes on at the catalyst surface may be responsible for the proceeding of two reactions: NO reduction with CO and direct NO decomposition.en
dc.publisherVersita, Warsaw
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142019/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142030/RS//
dc.rightsopenAccess
dc.sourceCentral European Journal of Chemistry
dc.subjectNO decompositionen
dc.subjectNO reductionen
dc.subjectPalladium catalisten
dc.subjectPerovskitesen
dc.titleCatalytic reduction of NO by CO over Pd-doped Perovskite-type catalystsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМехандјиев, Д.Р.; Кхристова, М.С.; Петровић, Срђан; Терлецки-Баричевић, Aна В.;
dc.citation.volume7
dc.citation.issue4
dc.citation.spage857
dc.citation.epage863
dc.citation.other7(4): 857-863
dc.citation.rankM22
dc.identifier.doi10.2478/s11532-009-0065-4
dc.identifier.rcubConv_4220
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/9249/619.pdf
dc.identifier.scopus2-s2.0-70349968237
dc.identifier.wos000270541000026
dc.type.versionpublishedVersion


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