Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte
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Electrochemical deposition/dissolution of aluminium to/from aluminium in deep eutectic solvent
(DES), made of the AlCl3+urea, at temperatures of 25 to 60°C have been investigated. The depositions were performed in potentiostatic modes. The morphology of the obtained deposits was characterized using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS).
Critical overpotential of aluminium deposition increased from around – 0.120 V at 25°C to
around – 0.050 V at 50°C. All recorded currents were generally speaking small, but would substantially increase with increasing working temperature (from 0.01 mA cm-2 up to 0.25 mA cm-2). Current/time transients recorded at overpotentials over – 0.100 V vs. Al indicate continuous three-dimensional nucleation and growth. Epitaxial growth over aluminium substrate was not observed under applied experimental conditions.
Electrodeposition/dissolution processes of aluminium under chosen conditions were reversible,
reproducible a...nd slow (relatively small current densities, bellow 0.3 mA cm-2). Polarization curves
recorded noticeable dependence of aluminium deposition/dissolution reversible potential on temperature applied.
The deposits obtained showed variety of morphological shapes (needles, rods, flakes, Fig.1)
depending on the working temperature and potential applied. All the deposits were made of crystallites grouped randomly into more or less separate agglomerates which were positioned over lower layer of densely populated much smaller crystallites. Lower layer showed good adherence to the substrate and exhibited high surface area. Density of the crystallites distribution over the substrate and complicity of the crystal forms increased with the potentials applied.
Keywords:
electrochemical depositionSource:
69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy, 2018Publisher:
- International Society of Electrochemistry
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IHTMTY - CONF AU - Cvetković, Vesna S. AU - Vukićević, Nataša M. AU - Jovićević, Niko AU - Jovićević, Jovan N. PY - 2018 UR - http://annual69.ise-online.org UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6154 AB - Electrochemical deposition/dissolution of aluminium to/from aluminium in deep eutectic solvent (DES), made of the AlCl3+urea, at temperatures of 25 to 60°C have been investigated. The depositions were performed in potentiostatic modes. The morphology of the obtained deposits was characterized using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Critical overpotential of aluminium deposition increased from around – 0.120 V at 25°C to around – 0.050 V at 50°C. All recorded currents were generally speaking small, but would substantially increase with increasing working temperature (from 0.01 mA cm-2 up to 0.25 mA cm-2). Current/time transients recorded at overpotentials over – 0.100 V vs. Al indicate continuous three-dimensional nucleation and growth. Epitaxial growth over aluminium substrate was not observed under applied experimental conditions. Electrodeposition/dissolution processes of aluminium under chosen conditions were reversible, reproducible and slow (relatively small current densities, bellow 0.3 mA cm-2). Polarization curves recorded noticeable dependence of aluminium deposition/dissolution reversible potential on temperature applied. The deposits obtained showed variety of morphological shapes (needles, rods, flakes, Fig.1) depending on the working temperature and potential applied. All the deposits were made of crystallites grouped randomly into more or less separate agglomerates which were positioned over lower layer of densely populated much smaller crystallites. Lower layer showed good adherence to the substrate and exhibited high surface area. Density of the crystallites distribution over the substrate and complicity of the crystal forms increased with the potentials applied. PB - International Society of Electrochemistry C3 - 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy T1 - Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte UR - https://hdl.handle.net/21.15107/rcub_cer_6154 ER -
@conference{ author = "Cvetković, Vesna S. and Vukićević, Nataša M. and Jovićević, Niko and Jovićević, Jovan N.", year = "2018", abstract = "Electrochemical deposition/dissolution of aluminium to/from aluminium in deep eutectic solvent (DES), made of the AlCl3+urea, at temperatures of 25 to 60°C have been investigated. The depositions were performed in potentiostatic modes. The morphology of the obtained deposits was characterized using scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). Critical overpotential of aluminium deposition increased from around – 0.120 V at 25°C to around – 0.050 V at 50°C. All recorded currents were generally speaking small, but would substantially increase with increasing working temperature (from 0.01 mA cm-2 up to 0.25 mA cm-2). Current/time transients recorded at overpotentials over – 0.100 V vs. Al indicate continuous three-dimensional nucleation and growth. Epitaxial growth over aluminium substrate was not observed under applied experimental conditions. Electrodeposition/dissolution processes of aluminium under chosen conditions were reversible, reproducible and slow (relatively small current densities, bellow 0.3 mA cm-2). Polarization curves recorded noticeable dependence of aluminium deposition/dissolution reversible potential on temperature applied. The deposits obtained showed variety of morphological shapes (needles, rods, flakes, Fig.1) depending on the working temperature and potential applied. All the deposits were made of crystallites grouped randomly into more or less separate agglomerates which were positioned over lower layer of densely populated much smaller crystallites. Lower layer showed good adherence to the substrate and exhibited high surface area. Density of the crystallites distribution over the substrate and complicity of the crystal forms increased with the potentials applied.", publisher = "International Society of Electrochemistry", journal = "69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy", title = "Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte", url = "https://hdl.handle.net/21.15107/rcub_cer_6154" }
Cvetković, V. S., Vukićević, N. M., Jovićević, N.,& Jovićević, J. N.. (2018). Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte. in 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy International Society of Electrochemistry.. https://hdl.handle.net/21.15107/rcub_cer_6154
Cvetković VS, Vukićević NM, Jovićević N, Jovićević JN. Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte. in 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy. 2018;. https://hdl.handle.net/21.15107/rcub_cer_6154 .
Cvetković, Vesna S., Vukićević, Nataša M., Jovićević, Niko, Jovićević, Jovan N., "Electrochemical Deposition of Aluminium on Aluminium from Ureabased Electrolyte" in 69th Annual Meeting of the International society of Electrochemistry, 2 - 7 September 2018, Bologna, Italy (2018), https://hdl.handle.net/21.15107/rcub_cer_6154 .