Investigation of sorption behavior of Cu(II) and Pb(II) onto a novеl EDTA modified copolymer

2021
Authors
Tadić, Tamara
Marković, Bojana

Stefanović, Ivan

Džunuzović, Jasna

Sandić, Zvjezdana

Suručić, Ljiljana

Onjia, Antonije

Conference object (Published version)
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Show full item recordAbstract
A new metal-chelating glycidyl methacrylate based macroporous copolymer with
ethylenediaminetetraacetic acid functions was tested as a potential Cu(II) and Pb(II) ions sorbent from aqueous solutions. The sorption was studied in non-competitive batch experiments, by varying initial pH and metal concentration, contact time and temperature. Pseudo-first and pseudo-second order model, as well as Bangham, intra-particle and liquid film diffusion models were used to determine the nature of sorption kinetics and the rate of limiting step. Equilibrium sorption data were analyzed with Langmuir, Freundlich, Temkin and Elovich isotherm models.
Keywords:
macroporous copolymer / sorption / isotherm modelsSource:
Proceedings - 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2021, September 20-24 2021, Belgrade, Serbia, 2021, 2, 505-508Publisher:
- Belgrade : Society of Physical Chemists of Serbia
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200135 (University of Belgrade, Faculty of Technology and Metallurgy) (RS-200135)
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Institution/Community
IHTMTY - CONF AU - Tadić, Tamara AU - Marković, Bojana AU - Stefanović, Ivan AU - Džunuzović, Jasna AU - Sandić, Zvjezdana AU - Suručić, Ljiljana AU - Onjia, Antonije PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6134 AB - A new metal-chelating glycidyl methacrylate based macroporous copolymer with ethylenediaminetetraacetic acid functions was tested as a potential Cu(II) and Pb(II) ions sorbent from aqueous solutions. The sorption was studied in non-competitive batch experiments, by varying initial pH and metal concentration, contact time and temperature. Pseudo-first and pseudo-second order model, as well as Bangham, intra-particle and liquid film diffusion models were used to determine the nature of sorption kinetics and the rate of limiting step. Equilibrium sorption data were analyzed with Langmuir, Freundlich, Temkin and Elovich isotherm models. PB - Belgrade : Society of Physical Chemists of Serbia C3 - Proceedings - 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2021, September 20-24 2021, Belgrade, Serbia T1 - Investigation of sorption behavior of Cu(II) and Pb(II) onto a novеl EDTA modified copolymer VL - 2 SP - 505 EP - 508 UR - https://hdl.handle.net/21.15107/rcub_cer_6134 ER -
@conference{ author = "Tadić, Tamara and Marković, Bojana and Stefanović, Ivan and Džunuzović, Jasna and Sandić, Zvjezdana and Suručić, Ljiljana and Onjia, Antonije", year = "2021", abstract = "A new metal-chelating glycidyl methacrylate based macroporous copolymer with ethylenediaminetetraacetic acid functions was tested as a potential Cu(II) and Pb(II) ions sorbent from aqueous solutions. The sorption was studied in non-competitive batch experiments, by varying initial pH and metal concentration, contact time and temperature. Pseudo-first and pseudo-second order model, as well as Bangham, intra-particle and liquid film diffusion models were used to determine the nature of sorption kinetics and the rate of limiting step. Equilibrium sorption data were analyzed with Langmuir, Freundlich, Temkin and Elovich isotherm models.", publisher = "Belgrade : Society of Physical Chemists of Serbia", journal = "Proceedings - 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2021, September 20-24 2021, Belgrade, Serbia", title = "Investigation of sorption behavior of Cu(II) and Pb(II) onto a novеl EDTA modified copolymer", volume = "2", pages = "505-508", url = "https://hdl.handle.net/21.15107/rcub_cer_6134" }
Tadić, T., Marković, B., Stefanović, I., Džunuzović, J., Sandić, Z., Suručić, L.,& Onjia, A.. (2021). Investigation of sorption behavior of Cu(II) and Pb(II) onto a novеl EDTA modified copolymer. in Proceedings - 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2021, September 20-24 2021, Belgrade, Serbia Belgrade : Society of Physical Chemists of Serbia., 2, 505-508. https://hdl.handle.net/21.15107/rcub_cer_6134
Tadić T, Marković B, Stefanović I, Džunuzović J, Sandić Z, Suručić L, Onjia A. Investigation of sorption behavior of Cu(II) and Pb(II) onto a novеl EDTA modified copolymer. in Proceedings - 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2021, September 20-24 2021, Belgrade, Serbia. 2021;2:505-508. https://hdl.handle.net/21.15107/rcub_cer_6134 .
Tadić, Tamara, Marković, Bojana, Stefanović, Ivan, Džunuzović, Jasna, Sandić, Zvjezdana, Suručić, Ljiljana, Onjia, Antonije, "Investigation of sorption behavior of Cu(II) and Pb(II) onto a novеl EDTA modified copolymer" in Proceedings - 15th International Conference on Fundamental and Applied Aspects of Physical Chemistry, Physical Chemistry 2021, September 20-24 2021, Belgrade, Serbia, 2 (2021):505-508, https://hdl.handle.net/21.15107/rcub_cer_6134 .