Recovery of Rare Earth Elements from Spent NdFeB Magnets: Metal Extraction by Molten Salt Electrolysis (Third Part)
Аутори
Chung, HanwenPrasakti, Laras
Stopić, Srećko
Feldhaus, Dominic
Cvetković, Vesna S.
Friedrich, Bernd
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The results obtained from the work on a concept of a recycling process for NdFeB magnets
to recover rare earth elements for remanufacturing similar magnets are presented. This paper
investigates the viability of extracting rare earth metals from magnet recycling-derived oxide (MRDO) by means of molten salt electrolysis. The MRDO was produced from spent NdFeB magnets through oxidation in air and subsequently carbothermic reduction under an 80 mbar Ar gas atmosphere. This MRDO contained roughly 33 wt.% Nd and 10 wt.% Pr. The electrochemical reduction process of the MRDO on molybdenum electrodes in NdF3 + LiF and NdF3 + PrF3 + LiF fused salts systems was investigated by cyclic voltammetry and chronoamperometry measurements. The resulting electrolytes and electrodes were examined after potentiostatic deposition by scanning electron microscopy (SEM), inductively coupled plasma optical emission spectroscopy (ICP-OES), and X-ray diffraction (XRD) analysis. The electrodeposited metals appear...ed to accumulate on the cathode and X-ray diffraction analysis confirmed the formation of metallic Nd and Pr on the working substrate. The suitability of the obtained alloy intended for the remanufacturing of NdFeB magnets was then evaluated.
Кључне речи:
recycling / molten salt electrolysi / rare earth element / magnetsИзвор:
Metals, 2023, 13, 3, 559-Издавач:
- MDPI
Финансирање / пројекти:
- DAAD ID: 337-00-19/2023-01/5
- Federal Ministry for Economic Affairs and Climate Action, grant number 273 EN
- Project “Sustainable recovery of rare earth elements (Nd, Pr, Dy) from spent magnets”
Институција/група
IHTMTY - JOUR AU - Chung, Hanwen AU - Prasakti, Laras AU - Stopić, Srećko AU - Feldhaus, Dominic AU - Cvetković, Vesna S. AU - Friedrich, Bernd PY - 2023 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/6107 AB - The results obtained from the work on a concept of a recycling process for NdFeB magnets to recover rare earth elements for remanufacturing similar magnets are presented. This paper investigates the viability of extracting rare earth metals from magnet recycling-derived oxide (MRDO) by means of molten salt electrolysis. The MRDO was produced from spent NdFeB magnets through oxidation in air and subsequently carbothermic reduction under an 80 mbar Ar gas atmosphere. This MRDO contained roughly 33 wt.% Nd and 10 wt.% Pr. The electrochemical reduction process of the MRDO on molybdenum electrodes in NdF3 + LiF and NdF3 + PrF3 + LiF fused salts systems was investigated by cyclic voltammetry and chronoamperometry measurements. The resulting electrolytes and electrodes were examined after potentiostatic deposition by scanning electron microscopy (SEM), inductively coupled plasma optical emission spectroscopy (ICP-OES), and X-ray diffraction (XRD) analysis. The electrodeposited metals appeared to accumulate on the cathode and X-ray diffraction analysis confirmed the formation of metallic Nd and Pr on the working substrate. The suitability of the obtained alloy intended for the remanufacturing of NdFeB magnets was then evaluated. PB - MDPI T2 - Metals T1 - Recovery of Rare Earth Elements from Spent NdFeB Magnets: Metal Extraction by Molten Salt Electrolysis (Third Part) VL - 13 IS - 3 SP - 559 DO - https://doi.org/10.3390/met13030559 ER -
@article{ author = "Chung, Hanwen and Prasakti, Laras and Stopić, Srećko and Feldhaus, Dominic and Cvetković, Vesna S. and Friedrich, Bernd", year = "2023", abstract = "The results obtained from the work on a concept of a recycling process for NdFeB magnets to recover rare earth elements for remanufacturing similar magnets are presented. This paper investigates the viability of extracting rare earth metals from magnet recycling-derived oxide (MRDO) by means of molten salt electrolysis. The MRDO was produced from spent NdFeB magnets through oxidation in air and subsequently carbothermic reduction under an 80 mbar Ar gas atmosphere. This MRDO contained roughly 33 wt.% Nd and 10 wt.% Pr. The electrochemical reduction process of the MRDO on molybdenum electrodes in NdF3 + LiF and NdF3 + PrF3 + LiF fused salts systems was investigated by cyclic voltammetry and chronoamperometry measurements. The resulting electrolytes and electrodes were examined after potentiostatic deposition by scanning electron microscopy (SEM), inductively coupled plasma optical emission spectroscopy (ICP-OES), and X-ray diffraction (XRD) analysis. The electrodeposited metals appeared to accumulate on the cathode and X-ray diffraction analysis confirmed the formation of metallic Nd and Pr on the working substrate. The suitability of the obtained alloy intended for the remanufacturing of NdFeB magnets was then evaluated.", publisher = "MDPI", journal = "Metals", title = "Recovery of Rare Earth Elements from Spent NdFeB Magnets: Metal Extraction by Molten Salt Electrolysis (Third Part)", volume = "13", number = "3", pages = "559", doi = "https://doi.org/10.3390/met13030559" }
Chung, H., Prasakti, L., Stopić, S., Feldhaus, D., Cvetković, V. S.,& Friedrich, B.. (2023). Recovery of Rare Earth Elements from Spent NdFeB Magnets: Metal Extraction by Molten Salt Electrolysis (Third Part). in Metals MDPI., 13(3), 559. https://doi.org/https://doi.org/10.3390/met13030559
Chung H, Prasakti L, Stopić S, Feldhaus D, Cvetković VS, Friedrich B. Recovery of Rare Earth Elements from Spent NdFeB Magnets: Metal Extraction by Molten Salt Electrolysis (Third Part). in Metals. 2023;13(3):559. doi:https://doi.org/10.3390/met13030559 .
Chung, Hanwen, Prasakti, Laras, Stopić, Srećko, Feldhaus, Dominic, Cvetković, Vesna S., Friedrich, Bernd, "Recovery of Rare Earth Elements from Spent NdFeB Magnets: Metal Extraction by Molten Salt Electrolysis (Third Part)" in Metals, 13, no. 3 (2023):559, https://doi.org/https://doi.org/10.3390/met13030559 . .