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Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources

Authorized Users Only
2009
Authors
Jugović, Branimir
Gvozdenović, Milica M.
Stevanović, Jasmina
Trišović, Tomislav
Grgur, Branimir N.
Article (Published version)
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Abstract
Polyaniline (PANI) on graphite electrode was synthesized electrochemically under galvanostatic condition at current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl and 0.25 mol dm-3 aniline monomer. Electrochemical characterization of the PANI electrode was performed in 0.5 mol dm-3 HCl using cyclic voltammetry and galvanostatic measurements. The overall charge capacity of the PANI electrode was estimated to be 0.154 mAh cm-2, which corresponds to 25% of the theoretical mass of PANI available for doping exchange. It was observed that during initial cyclization at low pH, the extent of PANI degradation products was insignificant and practically had no influence on the charge/discharge characteristics of the PANI electrode.
Keywords:
Electropolymerization / Polyaniline / Rechargeable power sources
Source:
Materials Chemistry and Physics, 2009, 114, 2-3, 939-942
Funding / projects:
  • Modifikacija metalnih i nemetalnih materijala elektroprovodnim polimerima za primenu u novim tehnologijama (RS-142044)

DOI: 10.1016/j.matchemphys.2008.10.069

ISSN: 0254-0584

WoS: 000263833500077

Scopus: 2-s2.0-58949099336
[ Google Scholar ]
39
36
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/599
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Jugović, Branimir
AU  - Gvozdenović, Milica M.
AU  - Stevanović, Jasmina
AU  - Trišović, Tomislav
AU  - Grgur, Branimir N.
PY  - 2009
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/599
AB  - Polyaniline (PANI) on graphite electrode was synthesized electrochemically under galvanostatic condition at current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl and 0.25 mol dm-3 aniline monomer. Electrochemical characterization of the PANI electrode was performed in 0.5 mol dm-3 HCl using cyclic voltammetry and galvanostatic measurements. The overall charge capacity of the PANI electrode was estimated to be 0.154 mAh cm-2, which corresponds to 25% of the theoretical mass of PANI available for doping exchange. It was observed that during initial cyclization at low pH, the extent of PANI degradation products was insignificant and practically had no influence on the charge/discharge characteristics of the PANI electrode.
T2  - Materials Chemistry and Physics
T1  - Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources
VL  - 114
IS  - 2-3
SP  - 939
EP  - 942
DO  - 10.1016/j.matchemphys.2008.10.069
ER  - 
@article{
author = "Jugović, Branimir and Gvozdenović, Milica M. and Stevanović, Jasmina and Trišović, Tomislav and Grgur, Branimir N.",
year = "2009",
abstract = "Polyaniline (PANI) on graphite electrode was synthesized electrochemically under galvanostatic condition at current density of 2.0 mA cm-2 from aqueous solution of 1.0 mol dm-3 HCl and 0.25 mol dm-3 aniline monomer. Electrochemical characterization of the PANI electrode was performed in 0.5 mol dm-3 HCl using cyclic voltammetry and galvanostatic measurements. The overall charge capacity of the PANI electrode was estimated to be 0.154 mAh cm-2, which corresponds to 25% of the theoretical mass of PANI available for doping exchange. It was observed that during initial cyclization at low pH, the extent of PANI degradation products was insignificant and practically had no influence on the charge/discharge characteristics of the PANI electrode.",
journal = "Materials Chemistry and Physics",
title = "Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources",
volume = "114",
number = "2-3",
pages = "939-942",
doi = "10.1016/j.matchemphys.2008.10.069"
}
Jugović, B., Gvozdenović, M. M., Stevanović, J., Trišović, T.,& Grgur, B. N.. (2009). Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources. in Materials Chemistry and Physics, 114(2-3), 939-942.
https://doi.org/10.1016/j.matchemphys.2008.10.069
Jugović B, Gvozdenović MM, Stevanović J, Trišović T, Grgur BN. Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources. in Materials Chemistry and Physics. 2009;114(2-3):939-942.
doi:10.1016/j.matchemphys.2008.10.069 .
Jugović, Branimir, Gvozdenović, Milica M., Stevanović, Jasmina, Trišović, Tomislav, Grgur, Branimir N., "Characterization of electrochemically synthesized PANI on graphite electrode for potential use in electrochemical power sources" in Materials Chemistry and Physics, 114, no. 2-3 (2009):939-942,
https://doi.org/10.1016/j.matchemphys.2008.10.069 . .

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